Charge and Energy Storage in Electrical Double Layers presents the basic scientific concepts and implementation of procedures devised to obtain capacitive energy from changes in the potential of electrical double layers when the salinity of solutions is changed. Capacitive deionization— the closely connected reciprocal process—is also considered. The book covers the fundamentals of electrical double layers and ions transport in porous media, the description of promising techniques of energy extraction, and the practical problems involved in each. It is written for scientists in academia and industry, and for graduate students working in supercapacitors, capacitive mixing and deionization.
1. Cover image - p. iv 2. Title page - p. iv 3. Table of Contents - p. iv 4. Copyright - p. iv 5. Contributors - p. ix 6. Section A: Fundamentals of the Electrical Double Layer - p. ix 7. Chapter 1: Charge and Potential Distribution in the Electrical Double Layer of Porous Materials: Models - p. ix 8. Chapter 2: Kinetics of Ion Transport in a Porous Electrode - p. 18 9. Chapter 3: The Electrical Double Layer as a Capacitor. Evaluation of Capacitance in Different Solutions: Effect of Ion Concentrations, Sizes, and Valencies - p. 37 10. Section B: Materials - p. 62 11. Chapter 4: Selection of Carbon Electrode Materials - p. 62 12. Section C: Capacitive Energy Extraction From Double Layer Expansion (CDLE) - p. 83 13. Chapter 5: Capacitive Energy Extraction From Double Layer Expansion (CDLE). Fundamentals of the Method - p. 83 14. Chapter 6: Capacitive Energy Extraction From CDLE: Implementation - p. 117 15. Section D: Capacitive Energy Extraction by Donnan Potential (CDP) - p. 140 16. Chapter 7: CDP: Fundamentals of the Method - p. 140 17. Section E: Capacitive Deionization (CDI) - p. 166 18. Chapter 8: Principles and Theoretical Models of CDI: Experimental Approaches - p. 166 19. Section F: Conclusions - p. 192 20. Chapter 9: Future and Perspectives of the Capacitive Techniques - p. 192 21. Index - p. 203
Charge and Energy Storage in Electrical Double Layers presents the basic scientific concepts and implementation of procedures devised to obtain capacitive energy from changes in the potential of electrical double layers when the salinity of solutions is changed. Capacitive deionization— the closely connected reciprocal process—is also considered. The book covers the fundamentals of electrical double layers and ions transport in porous media, the description of promising techniques of energy extraction, and the practical problems involved in each. It is written for scientists in academia and industry, and for graduate students working in supercapacitors, capacitive mixing and deionization.
1. Cover image - p. iv 2. Title page - p. iv 3. Table of Contents - p. iv 4. Copyright - p. iv 5. Contributors - p. ix 6. Section A: Fundamentals of the Electrical Double Layer - p. ix 7. Chapter 1: Charge and Potential Distribution in the Electrical Double Layer of Porous Materials: Models - p. ix 8. Chapter 2: Kinetics of Ion Transport in a Porous Electrode - p. 18 9. Chapter 3: The Electrical Double Layer as a Capacitor. Evaluation of Capacitance in Different Solutions: Effect of Ion Concentrations, Sizes, and Valencies - p. 37 10. Section B: Materials - p. 62 11. Chapter 4: Selection of Carbon Electrode Materials - p. 62 12. Section C: Capacitive Energy Extraction From Double Layer Expansion (CDLE) - p. 83 13. Chapter 5: Capacitive Energy Extraction From Double Layer Expansion (CDLE). Fundamentals of the Method - p. 83 14. Chapter 6: Capacitive Energy Extraction From CDLE: Implementation - p. 117 15. Section D: Capacitive Energy Extraction by Donnan Potential (CDP) - p. 140 16. Chapter 7: CDP: Fundamentals of the Method - p. 140 17. Section E: Capacitive Deionization (CDI) - p. 166 18. Chapter 8: Principles and Theoretical Models of CDI: Experimental Approaches - p. 166 19. Section F: Conclusions - p. 192 20. Chapter 9: Future and Perspectives of the Capacitive Techniques - p. 192 21. Index - p. 203