Reaction Engineering clearly and concisely covers the concepts and models of reaction engineering and then applies them to real-world reactor design. The book emphasizes that the foundation of reaction engineering requires the use of kinetics and transport knowledge to explain and analyze reactor behaviors.
The authors use readily understandable language to cover the subject, leaving readers with a comprehensive guide on how to understand, analyze, and make decisions related to improving chemical reactions and chemical reactor design. Worked examples, and over 20 exercises at the end of each chapter, provide opportunities for readers to practice solving problems related to the content covered in the book.
1. Chapter 1. Introduction - p. 1 2. Chapter 2. Fundamentals of Reaction Kinetics - p. 25 3. Abstract - p. 25 4. 2.1 Reaction Rate - p. 26 5. 2.2 Reaction Rate Equations - p. 30 6. 2.3 Effect of Temperature on Reaction Rate - p. 37 7. 2.4 Multiple Reactions - p. 44 8. 2.5 Transformation and Integration of Reaction Rate Equations - p. 52 9. 2.6 Heterogeneous Catalysis and Adsorption - p. 60 10. 2.7 Kinetics of Heterogeneous Catalytic Reactions - p. 67 11. 2.8 Determination of Kinetic Parameters - p. 77 12. 2.9 Procedure for Developing Reaction Rate Equation - p. 86 13. Further Reading - p. 87 14. Problems - p. 87 15. Chapter 3. Tank Reactor - p. 95 16. Abstract - p. 95 17. 3.1 Mass Balance for Tank Reactor - p. 96 18. 3.2 Design of Isothermal Batch Tank Reactor (Single Reaction) - p. 97 19. 3.3 Design of Isothermal Batch Tank Reactor (Multiple Reactions) - p. 103 20. 3.4 Reactor Volume for Continuous Tank Reactor (CSTR) - p. 111 21. 3.5 CSTR in Series and Parallel - p. 115 22. 3.6 Yield and Selectivity for Multiple Reactions in a Tank Reactor - p. 123 23. 3.7 Semibatch Tank Reactor - p. 133 24. 3.8 Nonisothermal Batch Reactor - p. 138 25. 3.9 Steady-State Operation of CSTR - p. 145 26. Summary - p. 151 27. Further Reading - p. 152 28. Problems - p. 152 29. Chapter 4. Tubular Reactor - p. 161 30. Abstract - p. 161 31. 4.1 Plug Flow - p. 161 32. 4.2 Design of Isothermal Tubular Reactor - p. 163 33. 4.3 Comparison of Reactor Volumes of Tubular and Tank Reactors - p. 178 34. 4.4 Recycle Reactor - p. 184 35. 4.5 Nonisothermal Tubular Reactor - p. 185 36. 4.6 Optimal Temperature Sequence for Tubular Reactors - p. 197 37. Further Reading - p. 203 38. Problems - p. 203 39. Chapter 5. Residence Time Distribution and Flow Models for Reactors - p. 213 40. Abstract - p. 213 41. 5.1 Residence Time Distribution - p. 214 42. 5.2 Experimental Determination of RTD - p. 218 43. 5.3 Statistical Eigenvalues of RTD - p. 224 44. 5.4 RTD of Ideal Reactors - p. 228 45. 5.5 Nonideal Flow Phenomenon - p. 234 46. 5.6 Nonideal Flow Models - p. 238 47. 5.7 Design of Nonideal Reactors - p. 251 48. 5.8 Mixing of Fluids in Flow Reactors - p. 256 49. Further Reading - p. 260 50. Problems - p. 260 51. Chapter 6. Chemical Reaction and Transport Phenomena in Heterogeneous System - p. 265 52. Abstract - p. 265 53. 6.1 Steps in Heterogeneous Reactions - p. 266 54. 6.2 Heat and Mass Transfer Between Bulk Fluid and the Catalyst External Surface - p. 270 55. 6.3 Gas Diffusion in Porous Media - p. 279 56. 6.4 Diffusion and Reaction in Porous Catalysts - p. 281 57. 6.5 Effect of Internal Diffusion on Selectivity of Multiple Reactions - p. 294 58. 6.6 Determination of Diffusion Impact on Heterogeneous Reactions - p. 297 59. 6.7 Effects of Diffusion on Experimental Measurement of Reaction Rate - p. 301 60. Further Reading - p. 305 61. Problems - p. 305 62. Chapter 7. Analysis and Design of Heterogeneous Catalytic Reactors - p. 311 63. Abstract - p. 311 64. 7.1 Transport Phenomena Inside Fixed Bed Reactors - p. 312 65. 7.2 Mathematical Model for Fixed Bed Reactor - p. 320 66. 7.3 Adiabatic Fixed Bed Reactor - p. 325 67. 7.4 Fixed Bed Reactor With Internal Heat Exchanger - p. 337 68. 7.5 Autothermal Fixed Bed Reactors - p. 347 69. 7.6 Parameter Sensitivity - p. 351 70. 7.7 Laboratory Catalytic Reactor - p. 355 71. Further Reading - p. 361 72. Problems - p. 361 73. Chapter 8. Fluidized Bed Reactor - p. 369 74. Chapter 9. Multiple-Phase Reactors - p. 405 75. Abstract - p. 405 76. 9.1 Gas–Liquid Reactions - p. 405 77. 9.2 Gas–Liquid Reactors - p. 412 78. 9.3 Gas–Liquid–Solid Reactions - p. 421 79. 9.4 Trickle Bed Reactors - p. 425 80. 9.5 Slurry Reactor - p. 431 81. Further Reading - p. 441 82. Problems - p. 441 83. Chapter 10. Fluid–Solid Noncatalytic Reaction Kinetics and Reactors - p. 445 84. Abstract - p. 445 85. 10.1 Fluid–Solid Noncatalytic Reactions and Their Applications - p. 446 86. 10.2 Reaction Rate of Particles in Different Shapes - p. 448 87. 10.3 Theoretical Models of Solid Reactions - p. 451 88. 10.4 Kinetic Analysis of Continuous Model - p. 452 89. 10.5 Kinetic Analysis at Constant Particle Size Using the Shrinking Core Model - p. 454 90. 10.6 Kinetic Analysis With Changing Particle Diameter Using the Shrinking Core Model - p. 466 91. 10.7 Microparticle Model - p. 473 92. 10.8 Chemical Vapor Deposition - p. 477 93. 10.9 Design of Fluid–Solid Noncatalytic Reactor - p. 479 94. Further Reading - p. 487 95. Problems - p. 487 96. Chapter 11. Fundamentals of Biochemical Reaction Engineering - p. 491 97. Chapter 12. Fundamentals of Polymerization Reaction Engineering - p. 541 98. Abstract - p. 541 99. 12.1 Overview - p. 542 100. 12.2 Kinetic Analysis - p. 544 101. 12.3 Analysis of Heat and Mass Transfers in the Polymerization Process - p. 585 102. 12.4 Design and Analysis of Polymerization Reactor - p. 589 103. References - p. 596 104. Further Reading - p. 596 105. Problems - p. 596 106. Chapter 13. Introduction to Electrochemical Reaction Engineering - p. 599 107. Abstract - p. 599 108. 13.1 Introduction - p. 599 109. 13.2 Special Issues in Electrochemical Reaction Engineering - p. 608 110. 13.3 Electrochemical Reactors - p. 629 111. References - p. 650 112. Further Reading - p. 650 113. Problems - p. 650 114. Index - p. 653
Reaction Engineering clearly and concisely covers the concepts and models of reaction engineering and then applies them to real-world reactor design. The book emphasizes that the foundation of reaction engineering requires the use of kinetics and transport knowledge to explain and analyze reactor behaviors.
The authors use readily understandable language to cover the subject, leaving readers with a comprehensive guide on how to understand, analyze, and make decisions related to improving chemical reactions and chemical reactor design. Worked examples, and over 20 exercises at the end of each chapter, provide opportunities for readers to practice solving problems related to the content covered in the book.
1. Chapter 1. Introduction - p. 1 2. Chapter 2. Fundamentals of Reaction Kinetics - p. 25 3. Abstract - p. 25 4. 2.1 Reaction Rate - p. 26 5. 2.2 Reaction Rate Equations - p. 30 6. 2.3 Effect of Temperature on Reaction Rate - p. 37 7. 2.4 Multiple Reactions - p. 44 8. 2.5 Transformation and Integration of Reaction Rate Equations - p. 52 9. 2.6 Heterogeneous Catalysis and Adsorption - p. 60 10. 2.7 Kinetics of Heterogeneous Catalytic Reactions - p. 67 11. 2.8 Determination of Kinetic Parameters - p. 77 12. 2.9 Procedure for Developing Reaction Rate Equation - p. 86 13. Further Reading - p. 87 14. Problems - p. 87 15. Chapter 3. Tank Reactor - p. 95 16. Abstract - p. 95 17. 3.1 Mass Balance for Tank Reactor - p. 96 18. 3.2 Design of Isothermal Batch Tank Reactor (Single Reaction) - p. 97 19. 3.3 Design of Isothermal Batch Tank Reactor (Multiple Reactions) - p. 103 20. 3.4 Reactor Volume for Continuous Tank Reactor (CSTR) - p. 111 21. 3.5 CSTR in Series and Parallel - p. 115 22. 3.6 Yield and Selectivity for Multiple Reactions in a Tank Reactor - p. 123 23. 3.7 Semibatch Tank Reactor - p. 133 24. 3.8 Nonisothermal Batch Reactor - p. 138 25. 3.9 Steady-State Operation of CSTR - p. 145 26. Summary - p. 151 27. Further Reading - p. 152 28. Problems - p. 152 29. Chapter 4. Tubular Reactor - p. 161 30. Abstract - p. 161 31. 4.1 Plug Flow - p. 161 32. 4.2 Design of Isothermal Tubular Reactor - p. 163 33. 4.3 Comparison of Reactor Volumes of Tubular and Tank Reactors - p. 178 34. 4.4 Recycle Reactor - p. 184 35. 4.5 Nonisothermal Tubular Reactor - p. 185 36. 4.6 Optimal Temperature Sequence for Tubular Reactors - p. 197 37. Further Reading - p. 203 38. Problems - p. 203 39. Chapter 5. Residence Time Distribution and Flow Models for Reactors - p. 213 40. Abstract - p. 213 41. 5.1 Residence Time Distribution - p. 214 42. 5.2 Experimental Determination of RTD - p. 218 43. 5.3 Statistical Eigenvalues of RTD - p. 224 44. 5.4 RTD of Ideal Reactors - p. 228 45. 5.5 Nonideal Flow Phenomenon - p. 234 46. 5.6 Nonideal Flow Models - p. 238 47. 5.7 Design of Nonideal Reactors - p. 251 48. 5.8 Mixing of Fluids in Flow Reactors - p. 256 49. Further Reading - p. 260 50. Problems - p. 260 51. Chapter 6. Chemical Reaction and Transport Phenomena in Heterogeneous System - p. 265 52. Abstract - p. 265 53. 6.1 Steps in Heterogeneous Reactions - p. 266 54. 6.2 Heat and Mass Transfer Between Bulk Fluid and the Catalyst External Surface - p. 270 55. 6.3 Gas Diffusion in Porous Media - p. 279 56. 6.4 Diffusion and Reaction in Porous Catalysts - p. 281 57. 6.5 Effect of Internal Diffusion on Selectivity of Multiple Reactions - p. 294 58. 6.6 Determination of Diffusion Impact on Heterogeneous Reactions - p. 297 59. 6.7 Effects of Diffusion on Experimental Measurement of Reaction Rate - p. 301 60. Further Reading - p. 305 61. Problems - p. 305 62. Chapter 7. Analysis and Design of Heterogeneous Catalytic Reactors - p. 311 63. Abstract - p. 311 64. 7.1 Transport Phenomena Inside Fixed Bed Reactors - p. 312 65. 7.2 Mathematical Model for Fixed Bed Reactor - p. 320 66. 7.3 Adiabatic Fixed Bed Reactor - p. 325 67. 7.4 Fixed Bed Reactor With Internal Heat Exchanger - p. 337 68. 7.5 Autothermal Fixed Bed Reactors - p. 347 69. 7.6 Parameter Sensitivity - p. 351 70. 7.7 Laboratory Catalytic Reactor - p. 355 71. Further Reading - p. 361 72. Problems - p. 361 73. Chapter 8. Fluidized Bed Reactor - p. 369 74. Chapter 9. Multiple-Phase Reactors - p. 405 75. Abstract - p. 405 76. 9.1 Gas–Liquid Reactions - p. 405 77. 9.2 Gas–Liquid Reactors - p. 412 78. 9.3 Gas–Liquid–Solid Reactions - p. 421 79. 9.4 Trickle Bed Reactors - p. 425 80. 9.5 Slurry Reactor - p. 431 81. Further Reading - p. 441 82. Problems - p. 441 83. Chapter 10. Fluid–Solid Noncatalytic Reaction Kinetics and Reactors - p. 445 84. Abstract - p. 445 85. 10.1 Fluid–Solid Noncatalytic Reactions and Their Applications - p. 446 86. 10.2 Reaction Rate of Particles in Different Shapes - p. 448 87. 10.3 Theoretical Models of Solid Reactions - p. 451 88. 10.4 Kinetic Analysis of Continuous Model - p. 452 89. 10.5 Kinetic Analysis at Constant Particle Size Using the Shrinking Core Model - p. 454 90. 10.6 Kinetic Analysis With Changing Particle Diameter Using the Shrinking Core Model - p. 466 91. 10.7 Microparticle Model - p. 473 92. 10.8 Chemical Vapor Deposition - p. 477 93. 10.9 Design of Fluid–Solid Noncatalytic Reactor - p. 479 94. Further Reading - p. 487 95. Problems - p. 487 96. Chapter 11. Fundamentals of Biochemical Reaction Engineering - p. 491 97. Chapter 12. Fundamentals of Polymerization Reaction Engineering - p. 541 98. Abstract - p. 541 99. 12.1 Overview - p. 542 100. 12.2 Kinetic Analysis - p. 544 101. 12.3 Analysis of Heat and Mass Transfers in the Polymerization Process - p. 585 102. 12.4 Design and Analysis of Polymerization Reactor - p. 589 103. References - p. 596 104. Further Reading - p. 596 105. Problems - p. 596 106. Chapter 13. Introduction to Electrochemical Reaction Engineering - p. 599 107. Abstract - p. 599 108. 13.1 Introduction - p. 599 109. 13.2 Special Issues in Electrochemical Reaction Engineering - p. 608 110. 13.3 Electrochemical Reactors - p. 629 111. References - p. 650 112. Further Reading - p. 650 113. Problems - p. 650 114. Index - p. 653
