Reactivity of P-H Group of Phosphorus Based Compounds bridges the gap between inorganic and organic phosphorus compounds, providing a basis to explore the myriad possibilities for synthesis of novel low and high molecular phosphorus-containing compounds. It covers well-documented reactions in detail, including: tautomerization, oxidation, reduction, alkylation, oxidation coupling, addition reaction to: carbon-carbon multiple bonds, Schiff base, isocyanates, nitriles, epoxides; addition to carbonyl group, Kabachnik- Fields reaction, cross-coupling reaction and more. In an accessible style complete with synthetic routes and figures, the resource then covers the reactivity of multiple P-H group members: phosphines, phosphine oxides, hypophosphorus acid, H-phosphinic acids and polys(alkylene H-phosphonate).
This valuable coverage supports the advancement of research and applications in this area for scientists solving a scientific problem or starting a variety of new projects, such as a new reaction for the synthesis of biologically active compounds, new methods of polymer synthesis or a new methodology for polymer modification.
1. Cover image - p. Cover 2. Title page - p. iii 3. Table of Contents - p. iii 4. Copyright - p. iv 5. About the Author - p. ix 6. Preface - p. xi 7. Chapter 1. Acidity and Tautomerization of P–H Group - p. 1 8. Chapter 2. Reactivity of P–H Group of Phosphines - p. 19 9. Abstract - p. 19 10. 2.1 Phosphine - p. 19 11. 2.2 Primary Phosphines (RPH2) - p. 38 12. 2.3 Primary Diphosphines - p. 56 13. 2.4 Secondary Phosphines R2PH - p. 64 14. 2.5 Secondary Diphosphines—RPH-R′-PRH - p. 97 15. 2.6 Phosphine–Borane Complexes - p. 100 16. 2.7 Conclusion - p. 131 17. References - p. 132 18. Chapter 3. Reactivity of P–H Group of Phosphine Oxides - p. 145 19. Chapter 4. Reactivity of P–H Group of Hypophosphorous Acid and Its Derivatives - p. 199 20. Chapter 5. Reactivity of P–H Group of H-Phosphinic Acid and Its Derivatives - p. 245 21. Chapter 6. Reactivity of P–H Group of H-Phosphonic Acid and Its Derivatives - p. 291 22. Abstract - p. 291 23. 6.1 H-Phosphonic Acid - p. 291 24. 6.2 Diesters of H-Phosphonic Acid (Dialkyl H-Phosphonates) - p. 296 25. 6.3 Conclusion - p. 393 26. References - p. 394 27. Chapter 7. Reactivity of P–H Group of Poly(alkylene H-phosphonate)s - p. 411 28. Index - p. 431
Reactivity of P-H Group of Phosphorus Based Compounds bridges the gap between inorganic and organic phosphorus compounds, providing a basis to explore the myriad possibilities for synthesis of novel low and high molecular phosphorus-containing compounds. It covers well-documented reactions in detail, including: tautomerization, oxidation, reduction, alkylation, oxidation coupling, addition reaction to: carbon-carbon multiple bonds, Schiff base, isocyanates, nitriles, epoxides; addition to carbonyl group, Kabachnik- Fields reaction, cross-coupling reaction and more. In an accessible style complete with synthetic routes and figures, the resource then covers the reactivity of multiple P-H group members: phosphines, phosphine oxides, hypophosphorus acid, H-phosphinic acids and polys(alkylene H-phosphonate).
This valuable coverage supports the advancement of research and applications in this area for scientists solving a scientific problem or starting a variety of new projects, such as a new reaction for the synthesis of biologically active compounds, new methods of polymer synthesis or a new methodology for polymer modification.
1. Cover image - p. Cover 2. Title page - p. iii 3. Table of Contents - p. iii 4. Copyright - p. iv 5. About the Author - p. ix 6. Preface - p. xi 7. Chapter 1. Acidity and Tautomerization of P–H Group - p. 1 8. Chapter 2. Reactivity of P–H Group of Phosphines - p. 19 9. Abstract - p. 19 10. 2.1 Phosphine - p. 19 11. 2.2 Primary Phosphines (RPH2) - p. 38 12. 2.3 Primary Diphosphines - p. 56 13. 2.4 Secondary Phosphines R2PH - p. 64 14. 2.5 Secondary Diphosphines—RPH-R′-PRH - p. 97 15. 2.6 Phosphine–Borane Complexes - p. 100 16. 2.7 Conclusion - p. 131 17. References - p. 132 18. Chapter 3. Reactivity of P–H Group of Phosphine Oxides - p. 145 19. Chapter 4. Reactivity of P–H Group of Hypophosphorous Acid and Its Derivatives - p. 199 20. Chapter 5. Reactivity of P–H Group of H-Phosphinic Acid and Its Derivatives - p. 245 21. Chapter 6. Reactivity of P–H Group of H-Phosphonic Acid and Its Derivatives - p. 291 22. Abstract - p. 291 23. 6.1 H-Phosphonic Acid - p. 291 24. 6.2 Diesters of H-Phosphonic Acid (Dialkyl H-Phosphonates) - p. 296 25. 6.3 Conclusion - p. 393 26. References - p. 394 27. Chapter 7. Reactivity of P–H Group of Poly(alkylene H-phosphonate)s - p. 411 28. Index - p. 431
