Strategies for Palladium-Catalyzed Non-directed and Directed C-H Bond Functionalization portrays the complete scope of these two aspects of C-H bond functionalization in a single volume for the first time. Featured topics include the influence of palladacyclic systems in C-H bond functionalization (need for newer catalytic systems for better efficiency), mechanistic aspect of the functionalization strategies leading to better systems, and applications of these methodologies to natural product synthesis and material synthesis.
1. Chapter 1. Introduction - p. 1 2. Chapter 2. Directed CH Bond Functionalization Strategies for Synthesis - p. 9 3. Chapter 3. Nondirected CH Bond Functionalizations of (Hetero)arenes - p. 49 4. Abstract - p. 49 5. 3.1 Introduction - p. 49 6. 3.2 Reactions With Halides - p. 50 7. 3.3 Reactions With Pseudohalides - p. 148 8. 3.4 Conclusion - p. 154 9. References - p. 155 10. Chapter 4. Palladium-Catalyzed Directed Arylation of Unactivated C(sp3)H Bonds - p. 167 11. Chapter 5. CH Bond Functionalization at the Benzene Core of Indoles and Indolines (Excluding C-2 and C-3) - p. 205 12. Chapter 6. Palladium-Catalyzed Carbonylative and Carboxylative CH Functionalization Reactions: Importance and Role of Regioselectivity - p. 233 13. Chapter 7. Flow Chemistry Perspective for CH Bond Functionalization - p. 275 14. Chapter 8. Directed Meta-Selective CH Bond Functionalizations - p. 289 15. Chapter 9. Recent Advances in Distal Aliphatic sp3 CH Functionalization - p. 327 16. Chapter 10. Palladacycles for Directed and Nondirected CH Bond Functionalization of (Hetero)arenes - p. 357 17. Chapter 11. Mechanistic/Organometallic Aspects of Palladium-Catalyzed CH Bond Functionalization - p. 417 18. Chapter 12. Recent Developments in Palladium-Catalyzed Natural Product Synthesis via CH Activation - p. 453 19. Index - p. 471
Strategies for Palladium-Catalyzed Non-directed and Directed C-H Bond Functionalization portrays the complete scope of these two aspects of C-H bond functionalization in a single volume for the first time. Featured topics include the influence of palladacyclic systems in C-H bond functionalization (need for newer catalytic systems for better efficiency), mechanistic aspect of the functionalization strategies leading to better systems, and applications of these methodologies to natural product synthesis and material synthesis.
1. Chapter 1. Introduction - p. 1 2. Chapter 2. Directed CH Bond Functionalization Strategies for Synthesis - p. 9 3. Chapter 3. Nondirected CH Bond Functionalizations of (Hetero)arenes - p. 49 4. Abstract - p. 49 5. 3.1 Introduction - p. 49 6. 3.2 Reactions With Halides - p. 50 7. 3.3 Reactions With Pseudohalides - p. 148 8. 3.4 Conclusion - p. 154 9. References - p. 155 10. Chapter 4. Palladium-Catalyzed Directed Arylation of Unactivated C(sp3)H Bonds - p. 167 11. Chapter 5. CH Bond Functionalization at the Benzene Core of Indoles and Indolines (Excluding C-2 and C-3) - p. 205 12. Chapter 6. Palladium-Catalyzed Carbonylative and Carboxylative CH Functionalization Reactions: Importance and Role of Regioselectivity - p. 233 13. Chapter 7. Flow Chemistry Perspective for CH Bond Functionalization - p. 275 14. Chapter 8. Directed Meta-Selective CH Bond Functionalizations - p. 289 15. Chapter 9. Recent Advances in Distal Aliphatic sp3 CH Functionalization - p. 327 16. Chapter 10. Palladacycles for Directed and Nondirected CH Bond Functionalization of (Hetero)arenes - p. 357 17. Chapter 11. Mechanistic/Organometallic Aspects of Palladium-Catalyzed CH Bond Functionalization - p. 417 18. Chapter 12. Recent Developments in Palladium-Catalyzed Natural Product Synthesis via CH Activation - p. 453 19. Index - p. 471
