Advanced Water Treatment: Adsorption discusses the application of adsorption in water purification. The book reviews research findings on the preparation of five different nano/microcellulose-based adsorbents, their characterization, the study of adsorption kinetics and isotherms, the determination of adsorption mechanisms, and an evaluation of adsorbents’ regeneration properties. The book describes modification microfibrillated cellulose (MFC), the use of succinic anhydride modified mercerized nanocellulose, and aminosilane and hydroxyapatite modified nanostructured MFC for the removal of heavy metals from aqueous solutions.
Final sections describe the use of aminosilane, epoxy and hydroxyapatite modified MFC as a promising alternative for H2S removal from aqueous solutions, along with new findings on the adsorption properties of carbonated hydroxyapatite modified MFC as multifunctional adsorbent for the removal of both cations and anions ions from water.
1. 1. Introduction - p. 5 2. 2. Chemically Modified Cellulose-based Adsorbents - p. 9 3. 3. Applications of Nanocellulose for Water Treatment - p. 40 4. 4. Objectives and Structure of the Work - p. 50 5. 5. Materials and Methods - p. 51 6. 6. Results and Discussion - p. 56 7. 7. Conclusions - p. 71 8. Chapter 2. Adsorption of dyes onto modified titanium dioxide - p. 85 9. List of Publications - p. 86 10. Nomenclature - p. 87 11. Abbreviations - p. 88 12. 1. Introduction - p. 88 13. 2. Objective of the Work - p. 112 14. 3. Materials and Methods - p. 113 15. 4. Results and Discussion - p. 119 16. 5. Conclusion - p. 149 17. Chapter 3. Cross-linked chitosan and β-cyclodextrin as functional adsorbents in water treatment - p. 161 18. List of Publications - p. 162 19. Nomenclature - p. 163 20. Abbreviations - p. 164 21. 1. Introduction - p. 166 22. 2. Chitosan, Cyclodextrin, and Their Properties - p. 167 23. 3. Functionalized Chitosan and Cyclodextrin Adsorbents - p. 171 24. 4. Applications of Cross-Linked Adsorbents in Water Treatment - p. 216 25. 5. Objectives and Structure of the Work - p. 221 26. 6. Experimental Section - p. 222 27. 7. Results and Discussion - p. 230 28. 8. Conclusions and Further Research - p. 247 29. Chapter 4. Novel sorbents from low-cost materials for water treatment - p. 265 30. List of Publications - p. 266 31. List of Symbols - p. 267 32. 1. Introduction - p. 270 33. 2. Literature Review - p. 274 34. 3. Industrial Solid Wastes - p. 302 35. 4. Objectives of the Study - p. 304 36. 5. Materials and Methods - p. 306 37. 6. Results and Discussion - p. 317 38. 7. Conclusions and Further Research - p. 339 39. Appendix A: Additional Tables - p. 344 40. Chapter 5. Sol–gel synthesized titanosilicates for the uptake of radionuclides - p. 361 41. List of Publications - p. 362 42. Nomenclature - p. 363 43. Abbreviations - p. 364 44. 1. Introduction - p. 365 45. 2. Sorption Theory - p. 368 46. 3. Titanosilicates for Radionuclide Uptake - p. 377 47. 4. Objectives and Structure of the Work - p. 395 48. 5. Experimental Section - p. 396 49. 6. Results and Discussion - p. 398 50. 7. Synopsis and Conclusions - p. 427 51. 8. Appendices - p. 429 52. Chapter 6. Hydrothermal carbonization in the synthesis of sustainable porous carbon materials for water treatment - p. 445 53. Chapter 7. Synthesis of hybrid bionanocomposites and their application for the removal of rare-earth elements from synthetic wastewater - p. 505 54. Chapter 8. Selective recovery of rare-earth elements from diluted aqueous streams using N- and O-coordination ligand–grafted organic–inorganic hybrid composites - p. 565 55. List of Publications - p. 567 56. Nomenclature - p. 568 57. Abbreviations - p. 569 58. 1. Introduction - p. 570 59. 2. Objectives and Goals - p. 586 60. 3. Materials and Methods - p. 589 61. 4. Functionalization of Silica for REE Sorption: Investigation of suitable silane and Preparation method - p. 594 62. 5. Hybridization of Silica with Chitosan for REE Sorption: Understanding the Role of Physical Modification and Conditioning of the Polymer - p. 599 63. 6. Hybridization of Silica with Carbon-based Materials: Exploiting Single-Pot and Step-by-Step Telescopic Synthetic Pathways for the Design of REE-Selective Hybrid Composites - p. 603 64. 7. Green, Economic, and Efficient Biosorbent Marine Algae for REE Adsorption - p. 608 65. 8. Characterization of the Materials - p. 611 66. 9. Discussion of Significant Findings and Future Remarks - p. 620 67. 10. Conclusion - p. 642 68. Index - p. 665
Advanced Water Treatment: Adsorption discusses the application of adsorption in water purification. The book reviews research findings on the preparation of five different nano/microcellulose-based adsorbents, their characterization, the study of adsorption kinetics and isotherms, the determination of adsorption mechanisms, and an evaluation of adsorbents’ regeneration properties. The book describes modification microfibrillated cellulose (MFC), the use of succinic anhydride modified mercerized nanocellulose, and aminosilane and hydroxyapatite modified nanostructured MFC for the removal of heavy metals from aqueous solutions.
Final sections describe the use of aminosilane, epoxy and hydroxyapatite modified MFC as a promising alternative for H2S removal from aqueous solutions, along with new findings on the adsorption properties of carbonated hydroxyapatite modified MFC as multifunctional adsorbent for the removal of both cations and anions ions from water.
1. 1. Introduction - p. 5 2. 2. Chemically Modified Cellulose-based Adsorbents - p. 9 3. 3. Applications of Nanocellulose for Water Treatment - p. 40 4. 4. Objectives and Structure of the Work - p. 50 5. 5. Materials and Methods - p. 51 6. 6. Results and Discussion - p. 56 7. 7. Conclusions - p. 71 8. Chapter 2. Adsorption of dyes onto modified titanium dioxide - p. 85 9. List of Publications - p. 86 10. Nomenclature - p. 87 11. Abbreviations - p. 88 12. 1. Introduction - p. 88 13. 2. Objective of the Work - p. 112 14. 3. Materials and Methods - p. 113 15. 4. Results and Discussion - p. 119 16. 5. Conclusion - p. 149 17. Chapter 3. Cross-linked chitosan and β-cyclodextrin as functional adsorbents in water treatment - p. 161 18. List of Publications - p. 162 19. Nomenclature - p. 163 20. Abbreviations - p. 164 21. 1. Introduction - p. 166 22. 2. Chitosan, Cyclodextrin, and Their Properties - p. 167 23. 3. Functionalized Chitosan and Cyclodextrin Adsorbents - p. 171 24. 4. Applications of Cross-Linked Adsorbents in Water Treatment - p. 216 25. 5. Objectives and Structure of the Work - p. 221 26. 6. Experimental Section - p. 222 27. 7. Results and Discussion - p. 230 28. 8. Conclusions and Further Research - p. 247 29. Chapter 4. Novel sorbents from low-cost materials for water treatment - p. 265 30. List of Publications - p. 266 31. List of Symbols - p. 267 32. 1. Introduction - p. 270 33. 2. Literature Review - p. 274 34. 3. Industrial Solid Wastes - p. 302 35. 4. Objectives of the Study - p. 304 36. 5. Materials and Methods - p. 306 37. 6. Results and Discussion - p. 317 38. 7. Conclusions and Further Research - p. 339 39. Appendix A: Additional Tables - p. 344 40. Chapter 5. Sol–gel synthesized titanosilicates for the uptake of radionuclides - p. 361 41. List of Publications - p. 362 42. Nomenclature - p. 363 43. Abbreviations - p. 364 44. 1. Introduction - p. 365 45. 2. Sorption Theory - p. 368 46. 3. Titanosilicates for Radionuclide Uptake - p. 377 47. 4. Objectives and Structure of the Work - p. 395 48. 5. Experimental Section - p. 396 49. 6. Results and Discussion - p. 398 50. 7. Synopsis and Conclusions - p. 427 51. 8. Appendices - p. 429 52. Chapter 6. Hydrothermal carbonization in the synthesis of sustainable porous carbon materials for water treatment - p. 445 53. Chapter 7. Synthesis of hybrid bionanocomposites and their application for the removal of rare-earth elements from synthetic wastewater - p. 505 54. Chapter 8. Selective recovery of rare-earth elements from diluted aqueous streams using N- and O-coordination ligand–grafted organic–inorganic hybrid composites - p. 565 55. List of Publications - p. 567 56. Nomenclature - p. 568 57. Abbreviations - p. 569 58. 1. Introduction - p. 570 59. 2. Objectives and Goals - p. 586 60. 3. Materials and Methods - p. 589 61. 4. Functionalization of Silica for REE Sorption: Investigation of suitable silane and Preparation method - p. 594 62. 5. Hybridization of Silica with Chitosan for REE Sorption: Understanding the Role of Physical Modification and Conditioning of the Polymer - p. 599 63. 6. Hybridization of Silica with Carbon-based Materials: Exploiting Single-Pot and Step-by-Step Telescopic Synthetic Pathways for the Design of REE-Selective Hybrid Composites - p. 603 64. 7. Green, Economic, and Efficient Biosorbent Marine Algae for REE Adsorption - p. 608 65. 8. Characterization of the Materials - p. 611 66. 9. Discussion of Significant Findings and Future Remarks - p. 620 67. 10. Conclusion - p. 642 68. Index - p. 665