Biocatalysis in Green Solvents offers a pragmatic overview and instruction in biocatalysis and enzymology of green solvents for sustainable industries and medicine, running from concept to application. Here, international experts in the field discuss structure-function relationships of enzymes in ionic liquids (ILs) and examine how enzymes act as selective catalysts for fine biochemical synthesis in non-aqueous environments. Several integral green biochemical processes of biocatalytic transformation and pure product separation are described in detail.
Application focused chapters discuss the role of biocatalysis in creating and implementing deep eutectic solvents, biomass derived solvents, sub and supercritical fluids, carbon dioxide biphasic systems, and enzymatic membrane reactors, as well as applying these biocatalytic processes in drug discovery and production.
1. Biocatalysis in Green Solvents - p. Page i 2. Cover - p. Page i 3. Title page - p. Page ii 4. Table of Contents - p. Page iii 5. Copyright - p. Page iii 6. Dedication - p. Page v 7. Contents - p. Page vii 8. List of contributors - p. Page viii 9. Foreword - p. Page viii 10. Preface - p. Page ix 11. List of Illustrations - p. Page xiv 12. List of Tables - p. Page xv 13. Chapter 1 : Biocatalysis, solvents, and green metrics in sustainable chemistry - p. Page xv 14. Chapter 2 : Nonconventional biocatalysis: from organic solvents to green solvents - p. Page 16 15. Chapter 3 : Activation and stabilization of enzymes using ionic liquid engineering - p. Page 48 16. Chapter 4 : Refolding ability of ionic liquids against denatured proteins - p. Page 78 17. Chapter 5 : Stability and stabilization of biocatalysts by ionic liquids - p. Page 100 18. Chapter 6 : Clean biocatalysis in sponge-like ionic liquids - p. Page 137 19. Chapter 7 : Biocatalysis in biphasic systems based on ionic liquids - p. Page 179 20. Chapter 8 : Biotransformations of carbohydrates in ionic liquids - p. Page 201 21. Chapter 9 : Recent progress in ionic liquid-assisted processing and extraction of biopolymers - p. Page 224 22. Chapter 10 : Ionic liquids for biomass biotransformation - p. Page 249 23. Chapter 11 : Biocatalysis in ionic liquids for a low carbon future - p. Page 287 24. Chapter 12 : Application of ionic liquids in pharmaceutics and medicine - p. Page 313 25. Chapter 13 : Biocatalysis in subcritical and supercritical fluids - p. Page 360 26. Chapter 14 : Biocatalytic processes in ionic liquids and supercritical carbon dioxide biphasic systems - p. Page 394 27. Chapter 15 : Enzymatic membrane reactors and nonconventional solvents - p. Page 428 28. Chapter 16 : Applied biocatalysis in deep eutectic solvents - p. Page 459 29. Chapter 17 : Biocatalysis and green solvents: trends, needs, and opportunities - p. Page 504 30. Index - p. Page 524
Biocatalysis in Green Solvents offers a pragmatic overview and instruction in biocatalysis and enzymology of green solvents for sustainable industries and medicine, running from concept to application. Here, international experts in the field discuss structure-function relationships of enzymes in ionic liquids (ILs) and examine how enzymes act as selective catalysts for fine biochemical synthesis in non-aqueous environments. Several integral green biochemical processes of biocatalytic transformation and pure product separation are described in detail.
Application focused chapters discuss the role of biocatalysis in creating and implementing deep eutectic solvents, biomass derived solvents, sub and supercritical fluids, carbon dioxide biphasic systems, and enzymatic membrane reactors, as well as applying these biocatalytic processes in drug discovery and production.
1. Biocatalysis in Green Solvents - p. Page i 2. Cover - p. Page i 3. Title page - p. Page ii 4. Table of Contents - p. Page iii 5. Copyright - p. Page iii 6. Dedication - p. Page v 7. Contents - p. Page vii 8. List of contributors - p. Page viii 9. Foreword - p. Page viii 10. Preface - p. Page ix 11. List of Illustrations - p. Page xiv 12. List of Tables - p. Page xv 13. Chapter 1 : Biocatalysis, solvents, and green metrics in sustainable chemistry - p. Page xv 14. Chapter 2 : Nonconventional biocatalysis: from organic solvents to green solvents - p. Page 16 15. Chapter 3 : Activation and stabilization of enzymes using ionic liquid engineering - p. Page 48 16. Chapter 4 : Refolding ability of ionic liquids against denatured proteins - p. Page 78 17. Chapter 5 : Stability and stabilization of biocatalysts by ionic liquids - p. Page 100 18. Chapter 6 : Clean biocatalysis in sponge-like ionic liquids - p. Page 137 19. Chapter 7 : Biocatalysis in biphasic systems based on ionic liquids - p. Page 179 20. Chapter 8 : Biotransformations of carbohydrates in ionic liquids - p. Page 201 21. Chapter 9 : Recent progress in ionic liquid-assisted processing and extraction of biopolymers - p. Page 224 22. Chapter 10 : Ionic liquids for biomass biotransformation - p. Page 249 23. Chapter 11 : Biocatalysis in ionic liquids for a low carbon future - p. Page 287 24. Chapter 12 : Application of ionic liquids in pharmaceutics and medicine - p. Page 313 25. Chapter 13 : Biocatalysis in subcritical and supercritical fluids - p. Page 360 26. Chapter 14 : Biocatalytic processes in ionic liquids and supercritical carbon dioxide biphasic systems - p. Page 394 27. Chapter 15 : Enzymatic membrane reactors and nonconventional solvents - p. Page 428 28. Chapter 16 : Applied biocatalysis in deep eutectic solvents - p. Page 459 29. Chapter 17 : Biocatalysis and green solvents: trends, needs, and opportunities - p. Page 504 30. Index - p. Page 524