Comprehensive Inorganic Chemistry III, a ten-volume reference work, is intended to cover fundamental principles, recent discoveries, and significant applications of elements and their compounds. Authored by renowned experts in the field and edited by a world-class editorial board, each chapter provides a thorough and in-depth overview of the topic covered, featuring resources which will be useful to students, researchers, faculty as well as those in the industry.
Comprehensive Inorganic Chemistry III focuses on main group chemistry, biological inorganic chemistry, solid state and materials chemistry, catalysis, and new developments in electrochemistry and photochemistry, as well as NMR and diffraction methods for studying inorganic compounds.
The work expands on our 2013 work Comprehensive Inorganic Chemistry II while also adding new volumes on cutting-edge research areas and techniques for studying inorganic compounds. Researchers seeking background information on a specific problem involving the synthesis of inorganic compounds, as well as applications for numerous elements from the periodic table, and their compounds, will be able to rely on and refer to this authoritative scientific resource time and again.
This new work complements Comprehensive Coordination Chemistry III (2021) and Comprehensive Organometallic Chemistry IV (2022), constituting a formidable trio of reference resources covering the whole of modern inorganic chemistry.
1. 1.01. Introduction: Significance of molecular inorganic chemistry - p. 23 2. Section 1: Structure, Bonding, and Reactivity in Inorganic Molecular Systems - p. 42 3. 1.02. Main group metal coordination chemistry - p. 43 4. Abstract - p. 43 5. Abbreviations - p. 43 6. Acknowledgments - p. 44 7. 1.02.1 Introduction - p. 44 8. 1.02.2 Nitrogen-donor ligands - p. 45 9. 1.02.3 Phosphorus-donor ligands - p. 88 10. 1.02.4 Arsenic-donor ligands - p. 96 11. 1.02.5 Antimony-donor ligands - p. 152 12. 1.02.6 Oxygen-donor ligands - p. 152 13. 1.02.7 Sulfur-donor ligands - p. 172 14. 1.02.8 Selenium-donor ligands - p. 176 15. References - p. 178 16. 1.03. Low-coordinate compounds of heavier group 14–16 elements - p. 229 17. 1.04. Biradicals in main group chemistry: Synthesis, electronic structure, and application in small-molecule activation - p. 264 18. Abstract - p. 264 19. 1.04.1 Introduction - p. 264 20. 1.04.2 Theoretical description of biradicals - p. 266 21. 1.04.3 Main group biradicals - p. 292 22. 1.04.4 Applications of biradicals as molecular switches - p. 329 23. 1.04.5 Outlook: Beyond four and five-membered heterocyclic biradicals - p. 329 24. References - p. 329 25. Further reading - p. 329 26. Relevant websites - p. 329 27. 1.05. Nonclassical carbenes as noninnocent ligands - p. 335 28. 1.06. Frustrated lewis pairs in catalysis - p. 402 29. Chemistry with weakly coordinating aluminates [Al(ORF)4]− and borates [B(ORF)4]−: From fundamentals to application - p. 442 30. 1.08. Noble-gas chemistry - p. 523 31. Abstract - p. 523 32. Abbreviations - p. 523 33. 1.08.1 Introduction - p. 523 34. 1.08.2 Synthesis and reactivity of XeF2 - p. 524 35. 1.08.3 Xenon(II) and krypton(II) compounds - p. 524 36. 1.08.4 Xenon(IV) compounds - p. 524 37. 1.08.5 Xenon(VI) compounds - p. 556 38. 1.08.6 Xenon(VIII) compounds - p. 576 39. 1.08.7 Noble-gas molecules characterized by matrix isolation - p. 578 40. 1.08.8 High-pressure noble-gas chemistry - p. 578 41. 1.08.9 Perspective and outlook - p. 578 42. References - p. 578 43. 1.09. Syntheses and molecular structures of cyclic selenoethers and their derivatives - p. 648 44. 1.10. [FeFe]-Hydrogenase mimics containing heavy p block elements - p. 689 45. Section 2: Intermolecular Interactions - p. 707 46. 1.11. Computational modeling and characterization of secondary bonding in compounds of late p-block elements - p. 708 47. 1.12. Halogen-bonded halogen(I) ion complexes - p. 734 48. 1.13. Chalcogen bonding in supramolecular structures, anion recognition, and catalysis - p. 762 49. 1.14. Supramolecular chemistry of p-block elements - p. 825 50. 1.15. Metallophilic interactions - p. 852 51. Section 3: Inorganic Chains, Rings, and Cages - p. 906 52. 1.16. Molecular boron clusters - p. 907 53. 1.17. Chain, ring, and cluster compounds of heavy group 13 elements (Al, Ga, In, Tl) - p. 970 54. 1.18. Aromatic compounds bearing heavy group 14 atoms in their molecular frameworks - p. 996 55. 1.19. Chain, ring, and cluster compounds of group 15 elements (P, As, Sb, Bi) - p. 1025 56. 1.20. Zintl chemistry: From Zintl ions to Zintl clusters - p. 1093 57. 1.21. Polychalcogen molecules, ligands, and ions Part 1: Homo- and heteronuclear chalcogen rings - p. 1140 58. 1.22. Polychalcogen molecules, ligands, and ions Part 2: Catenated acyclic molecules, ions, and p-block element derivatives - p. 1141 59. Catenated compounds in group 17—polyhalides - p. 1209 60. 1.24. Synthesis, carbon-polymetal bonding and applications of organometallic clusters - p. 1238 61. 2.01. Introduction: Bioinorganic chemistry and homogeneous biomimetic inorganic catalysis - p. 1256 62. 2.02. Siderophores and iron transport - p. 1258 63. 2.03. Metal ion homeostasis: Metalloenzyme paralogs in the bacterial adaptative response to zinc restriction - p. 1276 64. 2.04. Metallomics and metalloproteomics - p. 1310 65. 2.05. Biomineralization - p. 1343 66. 2.06. Iron-sulfur clusters – functions of an ancient metal site - p. 1381 67. Abstract - p. 1381 68. Acknowledgments - p. 1381 69. 2.06.1 Introduction - p. 1381 70. 2.06.2 Type of centers and variability of coordination - p. 1382 71. 2.06.3 Direct catalysis at iron-sulfur clusters - p. 1382 72. 2.06.4 Iron-sulfur clusters involved in metabolic regulation - p. 1407 73. 2.06.5 The role of iron-sulfur clusters in DNA processing enzymes - p. 1420 74. 2.06.6 Conclusions - p. 1423 75. References - p. 1424 76. 2.07. [FeFe]-hydrogenases: Structure, mechanism, and metallocluster biosynthesis - p. 1472 77. 2.08. Heme-containing proteins: Structures, functions, and engineering - p. 1498 78. 2.09. Engineering of hemoproteins - p. 1533 79. 2.10. The biochemistry and enzymology of zinc enzymes - p. 1554 80. 2.11. Cobalt enzymes - p. 1590 81. 2.12. Biological and synthetic nitrogen fixation - p. 1626 82. 2.13. Photosynthesis - p. 1670 83. 2.14. Bio-inspired catalysis - p. 1676 84. 2.15. Imaging - p. 1731 85. 2.16. Phosphorescent metal complexes for biomedical applications - p. 1828 86. 2.17. Photoactive metallodrugs - p. 1906 87. 2.18. Metallophores: How do human pathogens withdraw metal ions from the colonized host - p. 1939 88. The role of d-block metal ions in neurodegenerative diseases - p. 1970 89. 2.20. Metal ion interactions with nucleic acids - p. 1988 90. 2.21. Metal-mediated base pairs in nucleic acid duplexes - p. 1991 91. 2.22. Supramolecular metal-based molecules and materials for biomedical applications - p. 2013 92. 2.23. Metal complexes as chemotherapeutic agents - p. 2054 93. 2.24. Protein targets for anticancer metal based drugs - p. 2120 94. 2.25. Platinum anticancer drugs: Targeting and delivery - p. 2142 95. 2.26. Anti-cancer gold compounds - p. 2194 96. 3.01. Introduction: Theory and bonding of inorganic non-molecular systems - p. 2214 97. Section 1: Models for Extended Inorganic Structures - p. 2218 98. 3.02. Electronic structure of oxide and halide perovskites - p. 2219 99. 3.03. Bonding in boron rich borides - p. 2234 100. 3.04. The Zintl-Klemm concept and its broader extensions - p. 2285 101. 3.05. An introduction to the theory of inorganic solid surfaces - p. 2320 102. 3.06. Bond activation and formation on inorganic surfaces - p. 2351 103. Section 2: Tools for Electronic Structure Analysis - p. 2395 104. 3.07. Chemical bonding with plane waves - p. 2396 105. Abstract - p. 2396 106. Acknowledgments - p. 2396 107. 3.07.1 Part I: Foundations - p. 2396 108. 3.07.2 Part II: Methods - p. 2415 109. 3.07.3 Part III: Applications - p. 2459 110. 3.07.4 Computational details - p. 2473 111. References - p. 2473 112. 3.08. Chemical bonding analyses using wannier functions - p. 2520 113. 3.09. Chemical bonding analysis in position space - p. 2554 114. 3.10. The structures of inorganic crystals: A rational explanation from the chemical pressure approach and the anions in metallic matrices model - p. 2582 115. Section 3: Predictive Exploration of New Structures - p. 2618 116. 3.11. Energy landscapes in inorganic chemistry - p. 2619 117. Abstract - p. 2619 118. Acknowledgments - p. 2619 119. 3.11.1 Introduction - p. 2619 120. 3.11.2 General cost function landscape concepts - p. 2628 121. 3.11.3 Energy landscapes of isolated chemical systems - p. 2643 122. 3.11.4 Time and energy landscapes - p. 2656 123. 3.11.5 Energy landscapes in interaction with the environment - p. 2671 124. 3.11.6 General methods to explore and classify cost function and energy landscapes - p. 2698 125. 3.11.7 Applications - p. 2711 126. 3.11.8 Outlook - p. 2762 127. References - p. 2766 128. 3.12. First principles crystal structure prediction - p. 2843 129. 3.13. Crystal chemistry at high pressure - p. 2884 130. Section 4: Properties and Phenomena - p. 2927 131. 3.14. In silico modeling of inorganic thermoelectric materials - p. 2928 132. 3.15. Correlated electronic states in quasicrystals - p. 2949 133. 3.16. Chemical bonding principles in magnetic topological quantum materials - p. 3000 134. 4.01. Introduction: Solid state inorganic chemistry - p. 3022 135. 4.02. Inorganic nonlinear optical materials - p. 3024 136. 4.03. Thermoelectric materials - p. 3104 137. 4.04. Non-oxide p-block (semi-)metal chalcogenide cage compounds - p. 3159 138. 4.05. Piezoelectric and ferroelectric materials: Fundamentals, recent progress, and applications - p. 3270 139. 4.06. Intermetallic materials - p. 3305 140. 4.07. Critical charge transfer pairs in intermetallic superconductors - p. 3376 141. 4.08. Magnetic materials - p. 3396 142. 4.09. Luminescence in the solid state - p. 3409 143. 4.10. Battery materials - p. 3449 144. 4.11. The chemistry of quantum materials - p. 3499 145. 4.12. High pressure chemistry - p. 3508 146. 4.13. Mixed anion materials - p. 3552 147. 4.14. The zoology of two-dimensional van der waals materials - p. 3584 148. 4.15. A practical guide to Three-dimensional halide perovskites: Structure, synthesis, and measurement - p. 3643 149. 4.16. Solid state inorganic color pigments: Ancient to modern - p. 3697 150. 4.17. Photoelectrochemical materials for solar energy conversion - p. 3744 151. 4.18. High temperature hydrothermal synthesis of inorganic compounds - p. 3748 152. 4.19. Solid-state electrolytes for lithium-ion batteries - p. 3777 153. 4.20. High pressure studies of transition metal oxides - p. 3791 154. 5.01. Introduction: Inorganic materials chemistry - p. 3817 155. 5.02. Data-driven materials discovery and synthesis using machine learning methods - p. 3820 156. 5.03. Metathesis routes to materials - p. 3836 157. 5.04. Solvothermal and hydrothermal methods for preparative solid-state chemistry - p. 3850 158. 5.05. Spark plasma sintering routes to consolidated inorganic functional materials - p. 3921 159. 5.06. Hydride precursors in materials synthesis - p. 3942 160. 5.07. Metal chalcogenide materials: Synthesis, structure and properties - p. 3958 161. 5.08. Preparation of magnetocaloric materials - p. 4000 162. 5.09. Materials synthesis for Na-ion batteries - p. 4026 163. 5.10. Crystalline inorganic materials from supertetrahedral chalcogenide clusters - p. 4053 164. 5.11. Designing new polar materials - p. 4080 165. 5.12. Max phases and mxenes - p. 4134 166. 5.13. Amorphization of hybrid framework materials - p. 4153 167. 5.14. Total scattering and pair distribution function analysis for studies of nanomaterials - p. 4179 168. 5.15. In situ/in operando diffraction studies of electrode materials in battery applications - p. 4214 169. 6.01. Introduction: A short history of single site catalysis - p. 4246 170. 6.02. Synthesis and application of (nano) zeolites - p. 4272 171. 6.03. Mesostructured materials - p. 4308 172. 6.04. Surface organometallic and coordination chemistry approach to formation of single site heterogeneous catalysts - p. 4345 173. 6.05. Challenges with atomically dispersed supported metal catalysts: Controlling performance, improving stability, and enhancing metal loading - p. 4369 174. 6.06. Metal containing nanoclusters in zeolites - p. 4400 175. 6.07. Single site spectroscopy of transition metal ions and reactive oxygen complexes in zeolites - p. 4451 176. 6.08. Dynamic evolution of catalytic active sites within zeolite catalysis - p. 4455 177. 6.09. Nanocluster heterogeneous catalysts: Insights from theory - p. 4490 178. 6.10. Imaging of single atom catalysts - p. 4524 179. 6.11. Metal-support interfaces in ceria-based catalysts - p. 4559 180. 6.12. Solid acid catalysis; Part I, the zeolite protonic site - p. 4603 181. 6.13. Solid acid catalysis; Part II, catalytic chemistry of proton activation - p. 4632 182. 6.14. Heterogeneous catalysts for the non-oxidative conversion of methane to aromatics and olefins - p. 4658 183. 6.15. Inorganic catalysis for methane conversion to chemicals - p. 4682 184. 6.16. Promoted Fischer-Tropsch catalysts - p. 4714 185. 6.17. Selective oxidation by mixed metal nanoparticles - p. 4729 186. 6.18. Doped semiconductor photocatalysts - p. 4751 187. 6.19. Structure-reactivity relations in electrocatalysis - p. 4770 188. 7.01. Introduction: Inorganic electrochemistry - p. 4802 189. 7.02. Status of Li(Na)-based anionic redox materials for better batteries - p. 4809 190. 7.03. Electrode materials for reversible sodium ions de/intercalation - p. 4873 191. 7.04. Electrode materials for K-ion batteries - p. 4916 192. 7.05. Charge transfer through interfaces in metal-ion intercalation systems - p. 4949 193. 7.06. Transition metal hexacyanoferrates as catalysts for (bio)sensors - p. 4983 194. 7.07. Conventional and less conventional solution-based synthesis of battery materials: Cathodes, anodes and electrolytes - p. 5000 195. 7.08. Nanostructured materials for electrochemical capacitors - p. 5033 196. 7.09. Development of polyanionic sodium-ion battery insertion materials - p. 5050 197. 7.10. Electrode materials viewed with transmission electron microscopy - p. 5096 198. 7.11. Chemistry of Li-air batteries - p. 5162 199. 7.12. Mineral inspired electrode materials for metal-ion batteries - p. 5183 200. 7.13. Computational design of materials for metal-ion batteries - p. 5222 201. 7.14. Lithium sulfur batteries: Electrochemistry and mechanistic research - p. 5233 202. 7.15. Fundamentals and applications of enzymatic bioelectrocatalysis - p. 5263 203. 7.16. Benchmarking in electrocatalysis - p. 5292 204. 8.01. Introduction: Inorganic photochemistry - p. 5377 205. 8.02. Luminescent transition-metal complexes and their applications in electroluminescence - p. 5378 206. 8.03. Non-sacrificial photocatalysis - p. 5482 207. 8.04. Redox photocatalysis - p. 5518 208. 8.05. Luminescence chemosensors, biological probes, and imaging reagents - p. 5538 209. 8.06. Photoactivated metal complexes for drug delivery - p. 5612 210. 8.07. Photochemical CO2 reduction - p. 5675 211. 8.08. Water oxidation catalysis in natural and artificial photosynthesis - p. 5697 212. 8.09. Photochromic materials - p. 5705 213. 8.10. Photochemically driven molecular machines based on coordination compounds - p. 5766 214. 8.11. Lanthanide-doped upconversion nanomaterials - p. 5804 215. 8.12. Lanthanides as luminescence imaging reagents - p. 5867 216. 8.13. Ultrafast dynamics of photoinduced processes in coordination compounds - p. 5886 217. 8.14. Luminescent supramolecular assemblies - p. 6007 218. 8.15. Multicomponent supramolecular photochemistry - p. 6117 219. 8.16. Recent progress and application of computational chemistry to understand inorganic photochemistry - p. 6166 220. 8.17. Structural characterization of excited state transition metal complexes by x-ray transient absorption spectroscopies - p. 6201 221. 8.18. d-d and charge transfer photochemistry of 3d metal complexes - p. 6218 222. 8.19. Luminescence properties of the actinides and actinyls - p. 6239 223. 9.01. Introduction: NMR of inorganic nuclei - p. 6265 224. 9.02. Nitrogen-14 NMR spectroscopy - p. 6268 225. 9.03. 19F NMR on polymers - p. 6291 226. 9.04. Applications of 17O and 51V NMR in inorganic and bioinorganic chemistry - p. 6308 227. 9.05. NMR of carboranes - p. 6349 228. 9.06. Applications of silicon-29 NMR spectroscopy - p. 6395 229. 9.07. High field solid-state nmr of challenging nuclei in inorganic systems - p. 6446 230. 9.08. Solid state nmr of the rare earth nuclei: Applications in solid-state inorganic chemistry - p. 6509 231. 9.09. Solution NMR spectroscopy of single-molecule magnets - p. 6534 232. 9.10. Nmr of magnetic materials: Determination of magnetic structures by “on-site” nmr measurements - p. 6553 233. 9.11. Solid-state nmr studies of halide perovskite materials with photoconversion potential - p. 6603 234. 9.12. Solid-state NMR of energy storage materials - p. 6634 235. 9.13. A review of exotic quadrupolar metal nmr in mofs - p. 6711 236. 9.14. Dynamic nuclear polarization in inorganic solids from paramagnetic metal ion dopants - p. 6767 237. 9.15. NMR of nanoparticles - p. 6787 238. 9.16. NMR studies of 2D and pseudo-2D systems - p. 6872 239. 9.17. NMR of catalytic sites - p. 6904 240. 9.18. The expanding frontier between mechanochemistry & solid state NMR: Special focus on inorganic components of materials - p. 6935 241. 9.19. Advances in the characterization of inorganic solids using NMR correlation experiments - p. 6954 242. 9.20. Solid-state nmr of glasses - p. 7000 243. 9.21. Solution NMR of transition metal complexes - p. 7040 244. 9.22. Transition metal nmr thermometry - p. 7054 245. 9.23. Gas-phase NMR of nuclei other than 1H and 13C - p. 7089 246. 9.24. Applications of NMR spectroscopy in cultural heritage science - p. 7108 247. 9.25. Advances in the computation of nmr parameters for inorganic nuclides - p. 7173 248. 10.01. Introduction: X-ray, neutron and electron scattering methods in inorganic chemistry - p. 7198 249. 10.02. Neutron scattering studies of materials for hydrogen storage - p. 7200 250. 10.03. Structural studies of inorganic materials by electron crystallography - p. 7221 251. 10.04. Synchrotron diffraction studies on spin crossover materials - p. 7277 252. 10.05. EXAFS studies of inorganic catalytic materials - p. 7294 253. 10.06. Coherent x-ray diffraction studies of inorganic crystalline nanomaterials - p. 7349 254. 10.07. Panoramic (in beam) studies of materials synthesis - p. 7404 255. 10.08. X-ray diffraction methods for high-pressure solid-state synthesis - p. 7418 256. 10.09. Local structure determination using total scattering data - p. 7450 257. 10.10. In situ scattering studies of material formation during wet-chemical syntheses - p. 7489 258. 10.11. Time resolved structural studies in molecular materials - p. 7508 259. 10.12. Direct observation of transient species and chemical reactions in a pore observed by synchrotron radiation - p. 7553 260. 10.13. X-ray transient absorption spectroscopies in the study of excited state structures - p. 7613 261. 10.14. X-ray and neutron diffraction from glasses and liquids - p. 7678 262. 10.15. An overview of platon/pluton crystal structure validation - p. 7746 263. 10.16. Ab initio structure solution using synchrotron powder diffraction - p. 7779 264. Index - p. 7828 265. Author Index - p. 7869
Comprehensive Inorganic Chemistry III, a ten-volume reference work, is intended to cover fundamental principles, recent discoveries, and significant applications of elements and their compounds. Authored by renowned experts in the field and edited by a world-class editorial board, each chapter provides a thorough and in-depth overview of the topic covered, featuring resources which will be useful to students, researchers, faculty as well as those in the industry.
Comprehensive Inorganic Chemistry III focuses on main group chemistry, biological inorganic chemistry, solid state and materials chemistry, catalysis, and new developments in electrochemistry and photochemistry, as well as NMR and diffraction methods for studying inorganic compounds.
The work expands on our 2013 work Comprehensive Inorganic Chemistry II while also adding new volumes on cutting-edge research areas and techniques for studying inorganic compounds. Researchers seeking background information on a specific problem involving the synthesis of inorganic compounds, as well as applications for numerous elements from the periodic table, and their compounds, will be able to rely on and refer to this authoritative scientific resource time and again.
This new work complements Comprehensive Coordination Chemistry III (2021) and Comprehensive Organometallic Chemistry IV (2022), constituting a formidable trio of reference resources covering the whole of modern inorganic chemistry.
1. 1.01. Introduction: Significance of molecular inorganic chemistry - p. 23 2. Section 1: Structure, Bonding, and Reactivity in Inorganic Molecular Systems - p. 42 3. 1.02. Main group metal coordination chemistry - p. 43 4. Abstract - p. 43 5. Abbreviations - p. 43 6. Acknowledgments - p. 44 7. 1.02.1 Introduction - p. 44 8. 1.02.2 Nitrogen-donor ligands - p. 45 9. 1.02.3 Phosphorus-donor ligands - p. 88 10. 1.02.4 Arsenic-donor ligands - p. 96 11. 1.02.5 Antimony-donor ligands - p. 152 12. 1.02.6 Oxygen-donor ligands - p. 152 13. 1.02.7 Sulfur-donor ligands - p. 172 14. 1.02.8 Selenium-donor ligands - p. 176 15. References - p. 178 16. 1.03. Low-coordinate compounds of heavier group 14–16 elements - p. 229 17. 1.04. Biradicals in main group chemistry: Synthesis, electronic structure, and application in small-molecule activation - p. 264 18. Abstract - p. 264 19. 1.04.1 Introduction - p. 264 20. 1.04.2 Theoretical description of biradicals - p. 266 21. 1.04.3 Main group biradicals - p. 292 22. 1.04.4 Applications of biradicals as molecular switches - p. 329 23. 1.04.5 Outlook: Beyond four and five-membered heterocyclic biradicals - p. 329 24. References - p. 329 25. Further reading - p. 329 26. Relevant websites - p. 329 27. 1.05. Nonclassical carbenes as noninnocent ligands - p. 335 28. 1.06. Frustrated lewis pairs in catalysis - p. 402 29. Chemistry with weakly coordinating aluminates [Al(ORF)4]− and borates [B(ORF)4]−: From fundamentals to application - p. 442 30. 1.08. Noble-gas chemistry - p. 523 31. Abstract - p. 523 32. Abbreviations - p. 523 33. 1.08.1 Introduction - p. 523 34. 1.08.2 Synthesis and reactivity of XeF2 - p. 524 35. 1.08.3 Xenon(II) and krypton(II) compounds - p. 524 36. 1.08.4 Xenon(IV) compounds - p. 524 37. 1.08.5 Xenon(VI) compounds - p. 556 38. 1.08.6 Xenon(VIII) compounds - p. 576 39. 1.08.7 Noble-gas molecules characterized by matrix isolation - p. 578 40. 1.08.8 High-pressure noble-gas chemistry - p. 578 41. 1.08.9 Perspective and outlook - p. 578 42. References - p. 578 43. 1.09. Syntheses and molecular structures of cyclic selenoethers and their derivatives - p. 648 44. 1.10. [FeFe]-Hydrogenase mimics containing heavy p block elements - p. 689 45. Section 2: Intermolecular Interactions - p. 707 46. 1.11. Computational modeling and characterization of secondary bonding in compounds of late p-block elements - p. 708 47. 1.12. Halogen-bonded halogen(I) ion complexes - p. 734 48. 1.13. Chalcogen bonding in supramolecular structures, anion recognition, and catalysis - p. 762 49. 1.14. Supramolecular chemistry of p-block elements - p. 825 50. 1.15. Metallophilic interactions - p. 852 51. Section 3: Inorganic Chains, Rings, and Cages - p. 906 52. 1.16. Molecular boron clusters - p. 907 53. 1.17. Chain, ring, and cluster compounds of heavy group 13 elements (Al, Ga, In, Tl) - p. 970 54. 1.18. Aromatic compounds bearing heavy group 14 atoms in their molecular frameworks - p. 996 55. 1.19. Chain, ring, and cluster compounds of group 15 elements (P, As, Sb, Bi) - p. 1025 56. 1.20. Zintl chemistry: From Zintl ions to Zintl clusters - p. 1093 57. 1.21. Polychalcogen molecules, ligands, and ions Part 1: Homo- and heteronuclear chalcogen rings - p. 1140 58. 1.22. Polychalcogen molecules, ligands, and ions Part 2: Catenated acyclic molecules, ions, and p-block element derivatives - p. 1141 59. Catenated compounds in group 17—polyhalides - p. 1209 60. 1.24. Synthesis, carbon-polymetal bonding and applications of organometallic clusters - p. 1238 61. 2.01. Introduction: Bioinorganic chemistry and homogeneous biomimetic inorganic catalysis - p. 1256 62. 2.02. Siderophores and iron transport - p. 1258 63. 2.03. Metal ion homeostasis: Metalloenzyme paralogs in the bacterial adaptative response to zinc restriction - p. 1276 64. 2.04. Metallomics and metalloproteomics - p. 1310 65. 2.05. Biomineralization - p. 1343 66. 2.06. Iron-sulfur clusters – functions of an ancient metal site - p. 1381 67. Abstract - p. 1381 68. Acknowledgments - p. 1381 69. 2.06.1 Introduction - p. 1381 70. 2.06.2 Type of centers and variability of coordination - p. 1382 71. 2.06.3 Direct catalysis at iron-sulfur clusters - p. 1382 72. 2.06.4 Iron-sulfur clusters involved in metabolic regulation - p. 1407 73. 2.06.5 The role of iron-sulfur clusters in DNA processing enzymes - p. 1420 74. 2.06.6 Conclusions - p. 1423 75. References - p. 1424 76. 2.07. [FeFe]-hydrogenases: Structure, mechanism, and metallocluster biosynthesis - p. 1472 77. 2.08. Heme-containing proteins: Structures, functions, and engineering - p. 1498 78. 2.09. Engineering of hemoproteins - p. 1533 79. 2.10. The biochemistry and enzymology of zinc enzymes - p. 1554 80. 2.11. Cobalt enzymes - p. 1590 81. 2.12. Biological and synthetic nitrogen fixation - p. 1626 82. 2.13. Photosynthesis - p. 1670 83. 2.14. Bio-inspired catalysis - p. 1676 84. 2.15. Imaging - p. 1731 85. 2.16. Phosphorescent metal complexes for biomedical applications - p. 1828 86. 2.17. Photoactive metallodrugs - p. 1906 87. 2.18. Metallophores: How do human pathogens withdraw metal ions from the colonized host - p. 1939 88. The role of d-block metal ions in neurodegenerative diseases - p. 1970 89. 2.20. Metal ion interactions with nucleic acids - p. 1988 90. 2.21. Metal-mediated base pairs in nucleic acid duplexes - p. 1991 91. 2.22. Supramolecular metal-based molecules and materials for biomedical applications - p. 2013 92. 2.23. Metal complexes as chemotherapeutic agents - p. 2054 93. 2.24. Protein targets for anticancer metal based drugs - p. 2120 94. 2.25. Platinum anticancer drugs: Targeting and delivery - p. 2142 95. 2.26. Anti-cancer gold compounds - p. 2194 96. 3.01. Introduction: Theory and bonding of inorganic non-molecular systems - p. 2214 97. Section 1: Models for Extended Inorganic Structures - p. 2218 98. 3.02. Electronic structure of oxide and halide perovskites - p. 2219 99. 3.03. Bonding in boron rich borides - p. 2234 100. 3.04. The Zintl-Klemm concept and its broader extensions - p. 2285 101. 3.05. An introduction to the theory of inorganic solid surfaces - p. 2320 102. 3.06. Bond activation and formation on inorganic surfaces - p. 2351 103. Section 2: Tools for Electronic Structure Analysis - p. 2395 104. 3.07. Chemical bonding with plane waves - p. 2396 105. Abstract - p. 2396 106. Acknowledgments - p. 2396 107. 3.07.1 Part I: Foundations - p. 2396 108. 3.07.2 Part II: Methods - p. 2415 109. 3.07.3 Part III: Applications - p. 2459 110. 3.07.4 Computational details - p. 2473 111. References - p. 2473 112. 3.08. Chemical bonding analyses using wannier functions - p. 2520 113. 3.09. Chemical bonding analysis in position space - p. 2554 114. 3.10. The structures of inorganic crystals: A rational explanation from the chemical pressure approach and the anions in metallic matrices model - p. 2582 115. Section 3: Predictive Exploration of New Structures - p. 2618 116. 3.11. Energy landscapes in inorganic chemistry - p. 2619 117. Abstract - p. 2619 118. Acknowledgments - p. 2619 119. 3.11.1 Introduction - p. 2619 120. 3.11.2 General cost function landscape concepts - p. 2628 121. 3.11.3 Energy landscapes of isolated chemical systems - p. 2643 122. 3.11.4 Time and energy landscapes - p. 2656 123. 3.11.5 Energy landscapes in interaction with the environment - p. 2671 124. 3.11.6 General methods to explore and classify cost function and energy landscapes - p. 2698 125. 3.11.7 Applications - p. 2711 126. 3.11.8 Outlook - p. 2762 127. References - p. 2766 128. 3.12. First principles crystal structure prediction - p. 2843 129. 3.13. Crystal chemistry at high pressure - p. 2884 130. Section 4: Properties and Phenomena - p. 2927 131. 3.14. In silico modeling of inorganic thermoelectric materials - p. 2928 132. 3.15. Correlated electronic states in quasicrystals - p. 2949 133. 3.16. Chemical bonding principles in magnetic topological quantum materials - p. 3000 134. 4.01. Introduction: Solid state inorganic chemistry - p. 3022 135. 4.02. Inorganic nonlinear optical materials - p. 3024 136. 4.03. Thermoelectric materials - p. 3104 137. 4.04. Non-oxide p-block (semi-)metal chalcogenide cage compounds - p. 3159 138. 4.05. Piezoelectric and ferroelectric materials: Fundamentals, recent progress, and applications - p. 3270 139. 4.06. Intermetallic materials - p. 3305 140. 4.07. Critical charge transfer pairs in intermetallic superconductors - p. 3376 141. 4.08. Magnetic materials - p. 3396 142. 4.09. Luminescence in the solid state - p. 3409 143. 4.10. Battery materials - p. 3449 144. 4.11. The chemistry of quantum materials - p. 3499 145. 4.12. High pressure chemistry - p. 3508 146. 4.13. Mixed anion materials - p. 3552 147. 4.14. The zoology of two-dimensional van der waals materials - p. 3584 148. 4.15. A practical guide to Three-dimensional halide perovskites: Structure, synthesis, and measurement - p. 3643 149. 4.16. Solid state inorganic color pigments: Ancient to modern - p. 3697 150. 4.17. Photoelectrochemical materials for solar energy conversion - p. 3744 151. 4.18. High temperature hydrothermal synthesis of inorganic compounds - p. 3748 152. 4.19. Solid-state electrolytes for lithium-ion batteries - p. 3777 153. 4.20. High pressure studies of transition metal oxides - p. 3791 154. 5.01. Introduction: Inorganic materials chemistry - p. 3817 155. 5.02. Data-driven materials discovery and synthesis using machine learning methods - p. 3820 156. 5.03. Metathesis routes to materials - p. 3836 157. 5.04. Solvothermal and hydrothermal methods for preparative solid-state chemistry - p. 3850 158. 5.05. Spark plasma sintering routes to consolidated inorganic functional materials - p. 3921 159. 5.06. Hydride precursors in materials synthesis - p. 3942 160. 5.07. Metal chalcogenide materials: Synthesis, structure and properties - p. 3958 161. 5.08. Preparation of magnetocaloric materials - p. 4000 162. 5.09. Materials synthesis for Na-ion batteries - p. 4026 163. 5.10. Crystalline inorganic materials from supertetrahedral chalcogenide clusters - p. 4053 164. 5.11. Designing new polar materials - p. 4080 165. 5.12. Max phases and mxenes - p. 4134 166. 5.13. Amorphization of hybrid framework materials - p. 4153 167. 5.14. Total scattering and pair distribution function analysis for studies of nanomaterials - p. 4179 168. 5.15. In situ/in operando diffraction studies of electrode materials in battery applications - p. 4214 169. 6.01. Introduction: A short history of single site catalysis - p. 4246 170. 6.02. Synthesis and application of (nano) zeolites - p. 4272 171. 6.03. Mesostructured materials - p. 4308 172. 6.04. Surface organometallic and coordination chemistry approach to formation of single site heterogeneous catalysts - p. 4345 173. 6.05. Challenges with atomically dispersed supported metal catalysts: Controlling performance, improving stability, and enhancing metal loading - p. 4369 174. 6.06. Metal containing nanoclusters in zeolites - p. 4400 175. 6.07. Single site spectroscopy of transition metal ions and reactive oxygen complexes in zeolites - p. 4451 176. 6.08. Dynamic evolution of catalytic active sites within zeolite catalysis - p. 4455 177. 6.09. Nanocluster heterogeneous catalysts: Insights from theory - p. 4490 178. 6.10. Imaging of single atom catalysts - p. 4524 179. 6.11. Metal-support interfaces in ceria-based catalysts - p. 4559 180. 6.12. Solid acid catalysis; Part I, the zeolite protonic site - p. 4603 181. 6.13. Solid acid catalysis; Part II, catalytic chemistry of proton activation - p. 4632 182. 6.14. Heterogeneous catalysts for the non-oxidative conversion of methane to aromatics and olefins - p. 4658 183. 6.15. Inorganic catalysis for methane conversion to chemicals - p. 4682 184. 6.16. Promoted Fischer-Tropsch catalysts - p. 4714 185. 6.17. Selective oxidation by mixed metal nanoparticles - p. 4729 186. 6.18. Doped semiconductor photocatalysts - p. 4751 187. 6.19. Structure-reactivity relations in electrocatalysis - p. 4770 188. 7.01. Introduction: Inorganic electrochemistry - p. 4802 189. 7.02. Status of Li(Na)-based anionic redox materials for better batteries - p. 4809 190. 7.03. Electrode materials for reversible sodium ions de/intercalation - p. 4873 191. 7.04. Electrode materials for K-ion batteries - p. 4916 192. 7.05. Charge transfer through interfaces in metal-ion intercalation systems - p. 4949 193. 7.06. Transition metal hexacyanoferrates as catalysts for (bio)sensors - p. 4983 194. 7.07. Conventional and less conventional solution-based synthesis of battery materials: Cathodes, anodes and electrolytes - p. 5000 195. 7.08. Nanostructured materials for electrochemical capacitors - p. 5033 196. 7.09. Development of polyanionic sodium-ion battery insertion materials - p. 5050 197. 7.10. Electrode materials viewed with transmission electron microscopy - p. 5096 198. 7.11. Chemistry of Li-air batteries - p. 5162 199. 7.12. Mineral inspired electrode materials for metal-ion batteries - p. 5183 200. 7.13. Computational design of materials for metal-ion batteries - p. 5222 201. 7.14. Lithium sulfur batteries: Electrochemistry and mechanistic research - p. 5233 202. 7.15. Fundamentals and applications of enzymatic bioelectrocatalysis - p. 5263 203. 7.16. Benchmarking in electrocatalysis - p. 5292 204. 8.01. Introduction: Inorganic photochemistry - p. 5377 205. 8.02. Luminescent transition-metal complexes and their applications in electroluminescence - p. 5378 206. 8.03. Non-sacrificial photocatalysis - p. 5482 207. 8.04. Redox photocatalysis - p. 5518 208. 8.05. Luminescence chemosensors, biological probes, and imaging reagents - p. 5538 209. 8.06. Photoactivated metal complexes for drug delivery - p. 5612 210. 8.07. Photochemical CO2 reduction - p. 5675 211. 8.08. Water oxidation catalysis in natural and artificial photosynthesis - p. 5697 212. 8.09. Photochromic materials - p. 5705 213. 8.10. Photochemically driven molecular machines based on coordination compounds - p. 5766 214. 8.11. Lanthanide-doped upconversion nanomaterials - p. 5804 215. 8.12. Lanthanides as luminescence imaging reagents - p. 5867 216. 8.13. Ultrafast dynamics of photoinduced processes in coordination compounds - p. 5886 217. 8.14. Luminescent supramolecular assemblies - p. 6007 218. 8.15. Multicomponent supramolecular photochemistry - p. 6117 219. 8.16. Recent progress and application of computational chemistry to understand inorganic photochemistry - p. 6166 220. 8.17. Structural characterization of excited state transition metal complexes by x-ray transient absorption spectroscopies - p. 6201 221. 8.18. d-d and charge transfer photochemistry of 3d metal complexes - p. 6218 222. 8.19. Luminescence properties of the actinides and actinyls - p. 6239 223. 9.01. Introduction: NMR of inorganic nuclei - p. 6265 224. 9.02. Nitrogen-14 NMR spectroscopy - p. 6268 225. 9.03. 19F NMR on polymers - p. 6291 226. 9.04. Applications of 17O and 51V NMR in inorganic and bioinorganic chemistry - p. 6308 227. 9.05. NMR of carboranes - p. 6349 228. 9.06. Applications of silicon-29 NMR spectroscopy - p. 6395 229. 9.07. High field solid-state nmr of challenging nuclei in inorganic systems - p. 6446 230. 9.08. Solid state nmr of the rare earth nuclei: Applications in solid-state inorganic chemistry - p. 6509 231. 9.09. Solution NMR spectroscopy of single-molecule magnets - p. 6534 232. 9.10. Nmr of magnetic materials: Determination of magnetic structures by “on-site” nmr measurements - p. 6553 233. 9.11. Solid-state nmr studies of halide perovskite materials with photoconversion potential - p. 6603 234. 9.12. Solid-state NMR of energy storage materials - p. 6634 235. 9.13. A review of exotic quadrupolar metal nmr in mofs - p. 6711 236. 9.14. Dynamic nuclear polarization in inorganic solids from paramagnetic metal ion dopants - p. 6767 237. 9.15. NMR of nanoparticles - p. 6787 238. 9.16. NMR studies of 2D and pseudo-2D systems - p. 6872 239. 9.17. NMR of catalytic sites - p. 6904 240. 9.18. The expanding frontier between mechanochemistry & solid state NMR: Special focus on inorganic components of materials - p. 6935 241. 9.19. Advances in the characterization of inorganic solids using NMR correlation experiments - p. 6954 242. 9.20. Solid-state nmr of glasses - p. 7000 243. 9.21. Solution NMR of transition metal complexes - p. 7040 244. 9.22. Transition metal nmr thermometry - p. 7054 245. 9.23. Gas-phase NMR of nuclei other than 1H and 13C - p. 7089 246. 9.24. Applications of NMR spectroscopy in cultural heritage science - p. 7108 247. 9.25. Advances in the computation of nmr parameters for inorganic nuclides - p. 7173 248. 10.01. Introduction: X-ray, neutron and electron scattering methods in inorganic chemistry - p. 7198 249. 10.02. Neutron scattering studies of materials for hydrogen storage - p. 7200 250. 10.03. Structural studies of inorganic materials by electron crystallography - p. 7221 251. 10.04. Synchrotron diffraction studies on spin crossover materials - p. 7277 252. 10.05. EXAFS studies of inorganic catalytic materials - p. 7294 253. 10.06. Coherent x-ray diffraction studies of inorganic crystalline nanomaterials - p. 7349 254. 10.07. Panoramic (in beam) studies of materials synthesis - p. 7404 255. 10.08. X-ray diffraction methods for high-pressure solid-state synthesis - p. 7418 256. 10.09. Local structure determination using total scattering data - p. 7450 257. 10.10. In situ scattering studies of material formation during wet-chemical syntheses - p. 7489 258. 10.11. Time resolved structural studies in molecular materials - p. 7508 259. 10.12. Direct observation of transient species and chemical reactions in a pore observed by synchrotron radiation - p. 7553 260. 10.13. X-ray transient absorption spectroscopies in the study of excited state structures - p. 7613 261. 10.14. X-ray and neutron diffraction from glasses and liquids - p. 7678 262. 10.15. An overview of platon/pluton crystal structure validation - p. 7746 263. 10.16. Ab initio structure solution using synchrotron powder diffraction - p. 7779 264. Index - p. 7828 265. Author Index - p. 7869
