Comprehensive Organometallic Chemistry, Fifteen Volume Set is the market-leading resource covering all areas of this critical sub-discipline of chemistry. Divided into 15 clear sections, it provides expert coverage of the synthesis, structures, bonding and reactivity of all organometallic compounds, including the mechanisms of the reactions. Applications of organometallic chemistry, such as the role of these compounds as reagents and catalysts for organometallic transformations, and their participation in bioorganometallic chemistry, is then covered. This is a vibrant area, as illustrated by the fact that the 2001, 2005 and 2010 Nobel prizes in Chemistry are all concerned with organometallic chemistry. This new edition will therefore again provide an invaluable and efficient learning resource for all researchers and educators looking for up-to-date analysis of a particular aspect of organometallic chemistry.
1. 1.01. Introduction: Volume I - p. iii 2. 1.02. Models for Understanding Main Group and Transition Metal Bonding - p. iii 3. 1.03. Reversible Homolysis of Metal-Carbon Bonds - p. iii 4. 1.04. Very Low Oxidation States in Organometallic Chemistry - p. iii 5. 1.05. Very High Oxidation States in Organometallic Chemistry - p. iii 6. 1.06. Characterization Methods for Paramagnetic Organometallic Complexes - p. iii 7. 1.07. Computational Methods in Organometallic Chemistry - p. iii 8. 1.08. f-Element Organometallic Single-Molecule Magnets - p. iii 9. 1.09. Electrochemistry in Organometallic Chemistry - p. iii 10. 1.10. Organometallic Photosensitizers - p. iii 11. 1.11. Organometallic Chemistry of NHCs and Analogues - p. iii 12. 1.12. Ligands Featuring Covalently Tethered Moderate to Weakly Coordinating Anions - p. iii 13. 1.13. Redox-Active Ligands in Organometallic Chemistry - p. iii 14. 1.14. Proton Responsive and Hydrogen Bonding Ligands in Organometallic Chemistry - p. iii 15. 1.15. Introduction to the Organometallic Chemistry of Carbon Dioxide - p. iii 16. 1.16. Alkane σ-Complexes - p. iii 17. 1.17. Dinitrogen Binding and Functionalization - p. iii 18. 1.18. Lewis Acid Participation in Organometallic Chemistry - p. iii 19. 1.19. Organometallic Chemistry on Oxide Surfaces - p. iii 20. 1.20. Separation Strategies in Organometallic Catalysis - p. iii 21. 1.21. Impurities in Organometallic Catalysis - p. iii 22. 2.01. Introduction to Groups 1 to 2 - p. iii 23. 2.02. Organometallic Complexes of the Alkali Metals - p. iii 24. 2.03. Organometallic Complexes of the Alkaline Earth Metals - p. iii 25. Abstract - p. iii 26. Abbreviations - p. iii 27. Acknowledgments - p. iii 28. 2.03.1 Introduction - p. iii 29. 2.03.2 Beryllium - p. iii 30. 2.03.3 Magnesium - p. iii 31. 2.03.4 Calcium - p. iii 32. 2.03.5 Strontium and barium - p. iii 33. 2.03.6 Concluding remarks - p. iii 34. References - p. iii 35. 3.01. Introduction to Groups 3 to 4 and the f-Elements - p. iii 36. 3.02. Alkyl, carbonyl and cyanide complexes of the group 3 metals and lanthanides - p. iii 37. 3.03. Hydride, Alkyl, Aryl, Acetylide, Carbonyl, and Cyanide Complexes of the Actinides - p. iii 38. 3.04. Alkyl, Carbonyl and Cyanide Complexes of the Group 4 Metals - p. iii 39. N-Heterocyclic and Abnormal/Mesoionic Carbene Complexes of the Group 3 Metals and Lanthanides - p. iii 40. 3.06. N-Heterocyclic and Mesoionic Carbene Complexes of the Actinides - p. iii 41. 3.07. N-Heterocyclic and Mesoionic Carbene Complexes of the Group 4 Metals - p. iii 42. 3.08. Alkylidene Complexes of the Group 3 Metals and Lanthanides - p. iii 43. 3.09. Actinide Metal Carbene Complexes: Synthesis, Structure and Reactivity - p. iii 44. 3.10. Alkylidene Complexes of the Group 4 Transition Metals - p. iii 45. 3.11. Alkenes and Allyl Complexes of the Group 3 Metals and Lanthanides - p. iii 46. 3.12. Alkene, Alkyne and Allyl Complexes of the Actinides - p. iii 47. 3.13. Group 4 Metal Alkyne, Alkene, and Allyl Complexes - p. iii 48. 4.01. Buta- and Pentadienyl Complexes of the Group 3 Metals and Lanthanides - p. iii 49. 4.02. Buta- and Penta-Dienyl Complexes of the Actinides - p. iii 50. 4.03. Buta- and Penta-Dienyl Complexes of the Group 4 Metals - p. iii 51. 4.04. Cyclopentadienyls and Phospholyls of the Group 3 Metals and Lanthanides - p. iii 52. Abstract - p. iii 53. Abbreviations - p. iii 54. Acknowledgments - p. iii 55. 4.04.1 Group 3 and lanthanide cyclopentadienyl complexes - p. iii 56. References - p. iii 57. 4.05. Cyclopentadienyl and phospholyl compounds in organometallic actinide chemistry - p. iii 58. 4.06. Cyclopentadienyl and Phospholyl Complexes of the Group 4 Metals - p. iii 59. Abstract - p. iii 60. Nomenclature - p. iii 61. 4.06.1 Introduction - p. iii 62. 4.06.2 Titanium - p. iii 63. 4.06.3 Zirconium - p. iii 64. 4.06.4 Hafnium - p. iii 65. 4.06.5 Closing remarks - p. iii 66. References - p. iii 67. 4.07. Arene Complexes of the Group 3 Metals and Lanthanides - p. iii 68. 4.08. Arene Complexes of the Actinides - p. iii 69. 4.09. Arene Complexes of the Group 4 Metals - p. iii 70. 4.10. Larger Aromatic Complexes of the Group 3 Metals and Lanthanides - p. iii 71. Larger Aromatic Complexes of the Actinides - p. iii 72. 4.12. Larger Aromatic Complexes of the Group 4 Metals - p. iii 73. 5.01. Overview and Introduction - p. iii 74. 5.02. Cyclic and Non-Cyclic Pi Complexes of Vanadium - p. iii 75. 5.03. Cyclic and Non-Cyclic π-Complexes of Tantalum and Niobium - p. iii 76. 5.04. Cyclic and Non-cyclic Pi Complexes of Chromium - p. iii 77. Abstract - p. iii 78. 5.04.1 Introduction - p. iii 79. 5.04.2 η6-Arene chromium complexes - p. iii 80. 5.04.3 η6-Heteroarene chromium complexes - p. iii 81. 5.04.4 Other η6-pi-ligand chromium complexes - p. iii 82. 5.04.5 η5-Cyclopentadienyl chromium complexes - p. iii 83. 5.04.6 η5-Heterocyclopentadienyl chromium complexes - p. iii 84. 5.04.7 Other η5-pi-ligand chromium complexes - p. iii 85. 5.04.8 η2-Pi-ligand chromium complexes - p. iii 86. 5.04.9 η3-Pi-ligand chromium complexes - p. iii 87. 5.04.10 η4-Pi-ligand chromium complexes - p. iii 88. 5.04.11 η7-Pi-ligand chromium complexes - p. iii 89. 5.04.12 Summaries and suggestions - p. iii 90. References - p. iii 91. 5.05. Cyclic and Non-Cyclic Pi Complexes of Molybdenum - p. iii 92. Abstract - p. iii 93. 5.05.1 Cyclic π complexes of molybdenum - p. iii 94. 5.05.2 Non-cyclic π complexes of molybdenum - p. iii 95. 5.05.3 Summary and outlook - p. iii 96. References - p. iii 97. 5.06. Cyclic and Non-Cyclic Pi Complexes of Tungsten - p. iii 98. Abstract - p. iii 99. 5.06.1 Monoalkene complexes - p. iii 100. 5.06.2 Bis-alkene complexes - p. iii 101. 5.06.3 Allyl complexes - p. iii 102. 5.06.4 Monoalkyne complexes - p. iii 103. 5.06.5 Bis-alkyne complexes - p. iii 104. 5.06.6 Tris-alkyne complexes - p. iii 105. 5.06.7 Nitriles and heteroalkyne complexes - p. iii 106. 5.06.8 Carbonyl complexes - p. iii 107. 5.06.9 Imine and iminium complexes - p. iii 108. 5.06.10 Cyclopentadienyl complexes - p. iii 109. 5.06.11 Indenyl-tungsten complexes - p. iii 110. 5.06.12 Cyclobutadiene complexes - p. iii 111. 5.06.13 Arene complexes - p. iii 112. 5.06.14 Cycloheptatrienyl complexes - p. iii 113. 5.06.15 Summary - p. iii 114. References - p. iii 115. 5.07. Cyclic and Non-Cyclic Pi Complexes of Manganese - p. iii 116. Abstract - p. iii 117. Abbreviations - p. iii 118. Acknowledgments - p. iii 119. 5.07.1 Introduction and organization - p. iii 120. 5.07.2 Acyclic π ligands - p. iii 121. 5.07.3 Cyclic π ligands - p. iii 122. 5.07.4 Concluding remarks - p. iii 123. References - p. iii 124. 5.08. Organometallic Complexes of Technetium - p. iii 125. 5.09. Organometallic Complexes of Group 5 Metals With Metal-Carbon Sigma and Multiple Bonds - p. iii 126. 5.10. Group 6 Complexes With Metal-Carbon Sigma Bonds - p. iii 127. 5.11. Group 6 High Oxidation State Alkylidene and Alkylidyne Complexes - p. iii 128. Abstract - p. iii 129. 5.11.1 Introduction - p. iii 130. 5.11.2 Alkylidene complexes - p. iii 131. 5.11.3 Alkylidyne complexes - p. iii 132. 5.11.4 Pincer alkylidenes and alkylidynes - p. iii 133. 5.11.5 NHC alkylidene and alkylidyne complexes - p. iii 134. 5.11.6 Conclusions and perspective - p. iii 135. References - p. iii 136. 6.01. Complexes of Group 7 Metals with Metal-Carbon Sigma and Multiple Bonds - p. iii 137. Abstract - p. iii 138. Nomenclature - p. iii 139. 6.01.1 Introduction - p. iii 140. 6.01.2 Alkyl complexes - p. iii 141. 6.01.3 Aryl complexes - p. iii 142. 6.01.4 Vinyl complexes - p. iii 143. 6.01.5 Alkynyl complexes - p. iii 144. 6.01.6 Acyl and related complexes - p. iii 145. 6.01.7 Carbene complexes - p. iii 146. 6.01.8 Vinylidene and allenylidene complexes - p. iii 147. 6.01.9 Carbyne complexes - p. iii 148. 6.01.10 Metallacarbocycles - p. iii 149. 6.01.11 Conclusion - p. iii 150. References - p. iii 151. N-Heterocyclic and Mesoionic Carbene Complexes of Group 5 and Group 6 Metals - p. iii 152. 6.03. N-Heterocyclic and Mesoionic Carbene Complexes of Group 7 Metals - p. iii 153. 6.04. Organometallic Complexes of Group 5 With π-Acidic Ligands - p. iii 154. 6.05. Group VI Metal Complexes of Carbon Monoxide and Isocyanides - p. iii 155. Abstract - p. iii 156. Acknowledgments - p. iii 157. 6.05.1 Introduction - p. iii 158. 6.05.2 Homoleptic carbonyl complexes - p. iii 159. 6.05.3 Alkane complexes - p. iii 160. 6.05.4 Dihydrogen, hydride, borane-Lewis base adducts and σ-alane complexes - p. iii 161. 6.05.5 Complexes with silicon-containing ligands - p. iii 162. 6.05.6 Complexes with group VI metal–boron bonds - p. iii 163. 6.05.7 Complexes with group VI metal–nitrogen bonds - p. iii 164. 6.05.8 Complexes with group VI metal–phosphorus bonds - p. iii 165. 6.05.9 Complexes with group VI metal–oxygen bonds - p. iii 166. 6.05.10 Complexes with group VI metal–halide bonds - p. iii 167. 6.05.11 Complexes with group VI metal–gallium and indium bonds - p. iii 168. 6.05.12 Complexes with group VI metal–germanium, tin and lead bonds - p. iii 169. 6.05.13 Complexes with group VI metal–arsenic, antimony and bismuth bonds - p. iii 170. 6.05.14 Complexes with group VI metal–sulfur, selenium and tellurium bonds - p. iii 171. 6.05.15 Complexes that incorporate metallocenes - p. iii 172. 6.05.16 Group VI metal isocyanide complexes - p. iii 173. 6.05.17 Concluding remarks - p. iii 174. References - p. iii 175. 6.06. Carbonyl and Isocyanide Complexes of Manganese - p. iii 176. Abstract - p. iii 177. Abbreviations - p. iii 178. 6.06.1 Introduction - p. iii 179. 6.06.2 Brief discussion about Mn-CO starting materials and their preparation - p. iii 180. 6.06.3 Mn carbonyl complexes with monodentate ligands - p. iii 181. 6.06.4 Mn carbonyl complexes supported with bidentate ligands - p. iii 182. 6.06.5 Mn carbonyl complexes with tridentate “pincer” ligands - p. iii 183. 6.06.6 Mn carbonyl complexes with facially coordinating tridentate ligands - p. iii 184. 6.06.7 Mn carbonyl complexes with tetradentate ligands - p. iii 185. 6.06.8 Multinuclear Mn complexes with μ-X ligands (e.g., phosphido, thiolato, etc.) and clusters - p. iii 186. 6.06.9 Chemistry of Mn-CNR complexes - p. iii 187. 6.06.10 Mn-CO compounds in materials and supramolecular chemistry - p. iii 188. References - p. iii 189. 6.07. Carbonyl and Isocyanide Complexes of Rhenium - p. iii 190. 6.08. Organometallic Complexes of Group 5 Metals With Pincer and Noninnocent Ligands - p. iii 191. 6.09. Organometallic Pincer Complexes With Group 6 Metals - p. iii 192. 6.10. Organometallic Complexes of Group 7 Metals With Pincer and Noninnocent Ligands - p. iii 193. 6.11. Organometallic Tri- and Polynuclear Clusters of Tantalum, Niobium and Group 6 and 7 Transition Metals - p. iii 194. Complexes of Groups 5–7 with N2, NO, and Other N-Containing Small Molecules - p. iii 195. 7.01. Introduction to Groups 8 to 10 - p. iii 196. 7.02. Ferrocenes and Other Sandwich Complexes of Iron - p. iii 197. 7.03. Monocyclopentadienyl and Other Half-Sandwich Complexes of Iron - p. iii 198. Abstract - p. iii 199. Nomenclature - p. iii 200. 7.03.1 Introduction and historical perspectives - p. iii 201. 7.03.2 Monocyclopentadienyl compounds bearing classic π-acceptor ligands L - p. iii 202. 7.03.3 Monocyclopentadienyl compounds bearing halide and pseudohalide ligands - p. iii 203. 7.03.4 Monocyclopentadienyl compounds bearing group 15 donor ligands - p. iii 204. 7.03.5 Monocyclopentadienyl compounds bearing group 16 donor ligands - p. iii 205. 7.03.6 Monocyclopentadienyl compounds bearing group 14 donor ligands - p. iii 206. 7.03.7 Monocyclopentadienyl compounds bearing group 13 donor ligands - p. iii 207. 7.03.8 Monocyclopentadienyl iron hydride compounds - p. iii 208. 7.03.9 Heterobimetallic complexes featuring iron-metal bonds - p. iii 209. 7.03.10 Conclusion - p. iii 210. References - p. iii 211. 7.04. Recent Advances in Synthesis, Characterization and Reactivities of Iron-Alkyl and Iron-Aryl Complexes - p. iii 212. 7.05. Alkylidyne and Alkylidene Complexes of Iron - p. iii 213. 7.06. Small Molecule Activation by Organo-iron Complexes - p. iii 214. 7.07. Mono- and Bis-cyclopentadienyl Complexes of Ruthenium and Osmium - p. iii 215. Abstract - p. iii 216. 7.07.1 Introduction - p. iii 217. 7.07.2 Pogo stick type (one-legged piano stool) complexes - p. iii 218. 7.07.3 Two-legged piano stool complexes - p. iii 219. 7.07.4 Three-legged piano stool complexes - p. iii 220. 7.07.5 Four-legged piano stool complexes and penta- and hexahydrido complexes of osmium - p. iii 221. 7.07.6 Metallocenes and arene complexes of ruthenium and osmium - p. iii 222. 7.07.7 Concluding remarks - p. iii 223. References - p. iii 224. Ruthenium and Osmium Complexes Containing NHC and π-Acid Ligands - p. iii 225. Abstract - p. iii 226. Nomenclature - p. iii 227. Acknowledgment - p. iii 228. 7.08.1 General introduction - p. iii 229. 7.08.2 Complexes containing NHC ligands - p. iii 230. 7.08.3 Heavier tetrylenes - p. iii 231. 7.08.4 Nitrogen coordinating ligands - p. iii 232. 7.08.5 Phosphorous coordinating ligands - p. iii 233. References - p. iii 234. Relevant Websites - p. iii 235. Ruthenium benzylidene and benzylidyne complexes: Alkene metathesis catalysis - p. iii 236. 7.10. Ruthenium and Osmium Carbonyl Cluster Complexes - p. iii 237. 7.11. N-Heterocyclic Carbene Complexes of Cobalt - p. iii 238. Abstract - p. iii 239. Abbreviations - p. iii 240. Acknowledgments - p. iii 241. 7.11.1 General introduction - p. iii 242. 7.11.2 NHC cobalt complexes - p. iii 243. 7.11.3 General conclusion - p. iii 244. References - p. iii 245. 7.12. Organocobalt Complexes in C–H Bond Activation - p. iii 246. 7.13. Organometallic Pincer Complexes of Cobalt, Rhodium, and Iridium - p. iii 247. 8.01. N-Heterocyclic Carbene (NHC) Complexes of Rhodium and Iridium - p. iii 248. 8.02. Half-Sandwich Rhodium and Iridium Complexes - p. iii 249. Abstract - p. iii 250. Acknowledgment - p. iii 251. 8.02.1 Introduction - p. iii 252. 8.02.2 Half-sandwich Rh/Ir complexes with bidentate ligand of N and/or O atoms - p. iii 253. 8.02.3 Half-sandwich Rh/Ir complexes with phosphorus ligands - p. iii 254. 8.02.4 Half-sandwich Rh/Ir complexes with sulfur ligands - p. iii 255. 8.02.5 Half-sandwich rhodium-carbon or iridium-carbon bonded complexes - p. iii 256. 8.02.6 Half-sandwich Rh/Ir complexes bearing hydrogen, borane and metal groups - p. iii 257. 8.02.7 Half-sandwich Rh/Ir fragments in supramolecular chemistry - p. iii 258. 8.02.8 Conclusion - p. iii 259. References - p. iii 260. 8.03. Group 9 Boryl Complexes - p. iii 261. 8.04. Group 9 and 10 Carbonyl Clusters - p. iii 262. 8.05. Nickel-Carbon σ-Bonded Complexes - p. iii 263. Abstract - p. iii 264. 8.05.1 Introduction - p. iii 265. 8.05.2 Organonickel(II) complexes stabilized by tridentate ligands - p. iii 266. 8.05.3 Organonickel(II) complexes stabilized by bidentate ligands - p. iii 267. 8.05.4 Organonickel(II) complexes stabilized by monodentate ligands - p. iii 268. 8.05.5 Low-valent nickel complexes - p. iii 269. 8.05.6 High-valent nickel complexes - p. iii 270. 8.05.7 Dinuclear and mixed-valent nickel complexes - p. iii 271. 8.05.8 Conclusions and outlook - p. iii 272. References - p. iii 273. 8.06. Cyclopentadienyl Nickel Complexes - p. iii 274. 8.07. N-Heterocyclic Carbene Complexes of Nickel - p. iii 275. Abstract - p. iii 276. Abbreviations - p. iii 277. Acknowledgments - p. iii 278. 8.07.1 General Introduction - p. iii 279. 8.07.2 The Ni–N-heterocyclic carbene complexes - p. iii 280. 8.07.3 General Conclusion - p. iii 281. References - p. iii 282. 8.08. Palladium and Platinum NHC Complexes - p. iii 283. 8.09. Allyl-Palladium Complexes in Organic Synthesis - p. iii 284. 8.10. Zerovalent Nickel Organometallic Complexes - p. iii 285. 8.11. Monovalent Group 10 Organometallic Complexes - p. iii 286. 8.12. Trivalent and Tetravalent Palladium and Platinum Organometallic Complexes - p. iii 287. 9.01. Organometallic Complexes of Copper - p. iii 288. 9.02. Silver Organometallics - p. iii 289. 9.03. Zinc, Cadmium and Mercury - p. iii 290. 9.04. Recent Development in the Solution-State Chemistry of Boranes and Diboranes - p. iii 291. 9.05. Polyhedral Boranes and Carboranes - p. iii 292. 9.06. Polyhedral Metallaboranes and Metallacarboranes - p. iii 293. Abstract - p. iii 294. Nomenclature - p. iii 295. Acknowledgments - p. iii 296. 9.06.1 Introduction - p. iii 297. 9.06.2 Metallaborane clusters - p. iii 298. 9.06.3 Metallacarborane clusters - p. iii 299. 9.06.4 Supra-icosahedral metallaborane and metallacarborane clusters (Table 17) - p. iii 300. References - p. iii 301. 9.07. Gallium, Indium, and Thallium - p. iii 302. 10.01. Low-Valent Silicon Compounds - p. iii 303. 10.02. Compounds With Bonds Between Silicon and d-Block Metal Atoms - p. iii 304. 10.03. Organometallic Compounds of Germanium - p. iii 305. Abstract - p. iii 306. Nomenclature - p. iii 307. Acknowledgments - p. iii 308. 10.03.1 Introduction - p. iii 309. 10.03.2 Compounds containing germanium carbon bonds - p. iii 310. 10.03.3 Compounds with germanium group 17 element bonds - p. iii 311. 10.03.4 Compounds with germanium–hydrogen bonds - p. iii 312. 10.03.5 Compounds with germanium-group 15 element bonds - p. iii 313. 10.03.6 Compounds with germanium-group 16 element bonds - p. iii 314. 10.03.7 Compounds with germanium–metal (or metalloid) bonds - p. iii 315. 10.03.8 Germanium containing polymers - p. iii 316. 10.03.9 Germylenes - p. iii 317. 10.03.10 Compounds with germanium-germanium single bonds - p. iii 318. 10.03.11 Compounds with germanium-germanium multiple bonds - p. iii 319. 10.03.12 Conclusion - p. iii 320. References - p. iii 321. 10.04. Organometallic Compounds of Tin and Lead - p. iii 322. 10.05. Organometallic Compounds of Arsenic, Antimony and Bismuth - p. iii 323. 10.06. Frustrated Lewis Pair Systems - p. iii 324. Abstract - p. iii 325. 10.06.1 Introduction - p. iii 326. 10.06.2 Bond activation - p. iii 327. 10.06.3 Main group FLPs beyond phosphine-borane pairs - p. iii 328. 10.06.4 FLPs in catalysis - p. iii 329. 10.06.5 Mechanistic considerations - p. iii 330. 10.06.6 Transition metal Frustrated Lewis Pairs - p. iii 331. 10.06.7 Recent approaches and revising FLP-like systems - p. iii 332. 10.06.8 Conclusions - p. iii 333. References - p. iii 334. 11.01. Overview and Introduction - p. iii 335. 11.02. Lithium Complexes in Organic Synthesis - p. iii 336. 11.03. Sodium and Potassium Complexes in Organic Synthesis - p. iii 337. 11.04. Magnesium Complexes in Organic Synthesis - p. iii 338. 11.05. Calcium, Strontium and Barium Complexes in Organic Synthesis - p. iii 339. 11.06. Zinc Reagents in Organic Synthesis - p. iii 340. Abstract - p. iii 341. Acknowledgments - p. iii 342. 11.06.1 Introduction - p. iii 343. 11.06.2 Preparation of organozinc compounds - p. iii 344. 11.06.3 Applications of organozinc reagents in addition reactions - p. iii 345. 11.06.4 Applications of organozinc reagents in substitution reactions - p. iii 346. 11.06.5 Application of organozinc reagents in cross-coupling reactions - p. iii 347. 11.06.6 Catalytic applications using organozinc reagents - p. iii 348. 11.06.7 Reactivity of molecular zinc hydrides - p. iii 349. 11.06.8 Reactivity and applications of N-heterocyclic carbene zinc complexes - p. iii 350. 11.06.9 Organozinc pivalates as enhanced air- and moisture-stability reagents - p. iii 351. 11.06.10 Reactivity of heterometallic organozinc compounds - p. iii 352. 11.06.11 Conclusions - p. iii 353. References - p. iii 354. 11.07. Boron Complexes in Organic Synthesis - p. iii 355. Aluminum Complexes in Organic Synthesis - p. iii 356. 11.09. Gallium and Indium Complexes in Organic Synthesis - p. iii 357. 11.10. Silicon and Germanium Complexes in Organic Synthesis - p. iii 358. 11.11. Tin and Lead in Organic Synthesis - p. iii 359. 11.12. Antimony and Bismuth Complexes in Organic Synthesis - p. iii 360. 11.13. Selenium and Tellurium Complexes in Organic Synthesis - p. iii 361. 11.14. Frustrated Lewis Pairs in Organic Synthesis - p. iii 362. 11.15. Synergistic Effects of Multimetallic Main Group Complexes in Organic Synthesis - p. iii 363. 11.16. Main Group Complexes in Polymer Synthesis - p. iii 364. 12.01. Volume 12 and 13: Applications II. d- and f- Block Metal Complexes in Organic Synthesis - p. iii 365. 12.02. CC Bond Formation Through Heck-Like Reactions - p. iii 366. 12.03. Metal-Mediated Reductive C–C Coupling of π Bonds - p. iii 367. 12.04. C–C Bond Formation Through Cross-Electrophile Coupling Reactions - p. iii 368. 12.05. CC Bond Formation Through C-H Activation - p. iii 369. 12.06. Direct C–E (E = Boron, Halogen, Oxygen) Bond Formation Through C–H Activation - p. iii 370. 12.07. Synthetic Applications of Carbene and Nitrene CH Insertion - p. iii 371. 12.08. Metal-Catalyzed Amination: CN Bond Formation - p. iii 372. 12.09. Synthetic Applications of CC Bond Activation Reactions - p. iii 373. 12.10. Synthetic Applications of C–O and C–E Bond Activation Reactions - p. iii 374. 12.11. CF Bond Activation Reactions - p. iii 375. 12.12. Polymerization Reactions via Cross Coupling - p. iii 376. 13.01. Phosphine Ligand Development for Homogeneous Asymmetric Hydrogenation - p. iii 377. 13.02. Hydrometallation of Organometallic Complexes - p. iii 378. 13.03. Metal-Catalyzed Aerobic Oxidation Reactions - p. iii 379. 13.04. Metal-Mediated and Catalyzed Difunctionalization of Unsaturated Organics - p. iii 380. 13.05. Hydroformylation: Alternatives to Rh and Syn-gas - p. iii 381. 13.06. Reactions of Ylides Generated from MC Bonds - p. iii 382. E vs Z Selectivity in Olefin Metathesis Through Catalyst Design - p. iii 383. 13.08. Single-Electron Strategies in Organometallic Methods: Photoredox, Electrocatalysis, Radical Relay, and Beyond - p. iii 384. 13.09. Transition Metal-Catalyzed Copolymerization of Olefins With Polar Functional Monomers - p. iii 385. 13.10. Polymerization of Epoxides - p. iii 386. 13.11. Reaction Parameterization as a Tool for Development in Organometallic Catalysis - p. iii 387. 13.12. High-Throughput Experimentation in Organometallic Chemistry and Catalysis - p. iii 388. 14.01. Applications III. Materials Science, Nanoscience, Polymer Science and Surface Chemistry - p. iii 389. 14.02. Ferrocene and Related Metallocene Polymers - p. iii 390. 14.03. Conjugated Poly(metalla-ynes) - p. iii 391. 14.04. Organoboron and Related Group 13 Polymers - p. iii 392. 14.05. Organosilicon and Related Group 14 Polymers - p. iii 393. 14.06. Organophosphorus and Related Group 15 Polymers - p. iii 394. 14.07. Organometallic Dendrimers - p. iii 395. 14.08. Organometallic Functionalized MOFs - Reactivity and Catalysis - p. iii 396. 14.09. Organometallic Mesogens - p. iii 397. 14.10. Organometallic Complexes for Optoelectronic Applications - p. iii 398. 14.11. Organometallic Lanthanide Complexes as Single Molecule Magnets - p. iii 399. 14.12. Organometallic Receptors for Charged and Neutral Guest Species - p. iii 400. 14.13. Surface Organometallic Chemistry and Catalysis - p. iii 401. 14.14. Common Precursors and Surface Mechanisms for Atomic Layer Deposition - p. iii 402. 15.01. Introduction to Applications IV. Bio-Organometallics, Metallo-Therapy, Metallo-Diagnostics, Medicine and Environmental Chemistry - p. iii 403. 15.02. Hydrogenases and Model Complexes in Bioorganometallic Chemistry - p. iii 404. 15.03. Nitrogenases and Model Complexes in Bioorganometallic Chemistry - p. iii 405. Bioorganometallic Chemistry of Vitamin B12-Derivatives - p. iii 406. 15.05. Bioorganometallics: Artificial Metalloenzymes With Organometallic Moieties - p. iii 407. 15.06. Opportunities for interfacing organometallic catalysts with cellular metabolism - p. iii 408. 15.07. Oligonucleotide Complexes in Bioorganometallic Chemistry - p. iii 409. 15.08. Organometallic Receptors and Conjugates With Biomolecules in Bioorganometallic Chemistry - p. iii 410. 15.09. Organometallic Chemistry of Anticancer Ruthenium and Osmium Complexes - p. iii 411. 15.10. Organometallic Chemistry of Drugs Based on Technetium and Rhenium - p. iii 412. 15.11. Organometallic Chemistry of Drugs Based on Iron - p. iii 413. 15.12. Organometallic Chemistry of Gold-Based Drugs - p. iii 414. 15.13. Manganese-Based Carbon Monoxide-Releasing Molecules: A Multitude of Organometallic Pharmaceutical Candidates Primed for Further Biological Analysis - p. iii 415. 15.14. Organometallic Synthesis in Flow - p. iii 416. Index - p. iii 417. Authors - p. iii
Comprehensive Organometallic Chemistry, Fifteen Volume Set is the market-leading resource covering all areas of this critical sub-discipline of chemistry. Divided into 15 clear sections, it provides expert coverage of the synthesis, structures, bonding and reactivity of all organometallic compounds, including the mechanisms of the reactions. Applications of organometallic chemistry, such as the role of these compounds as reagents and catalysts for organometallic transformations, and their participation in bioorganometallic chemistry, is then covered. This is a vibrant area, as illustrated by the fact that the 2001, 2005 and 2010 Nobel prizes in Chemistry are all concerned with organometallic chemistry. This new edition will therefore again provide an invaluable and efficient learning resource for all researchers and educators looking for up-to-date analysis of a particular aspect of organometallic chemistry.
1. 1.01. Introduction: Volume I - p. iii 2. 1.02. Models for Understanding Main Group and Transition Metal Bonding - p. iii 3. 1.03. Reversible Homolysis of Metal-Carbon Bonds - p. iii 4. 1.04. Very Low Oxidation States in Organometallic Chemistry - p. iii 5. 1.05. Very High Oxidation States in Organometallic Chemistry - p. iii 6. 1.06. Characterization Methods for Paramagnetic Organometallic Complexes - p. iii 7. 1.07. Computational Methods in Organometallic Chemistry - p. iii 8. 1.08. f-Element Organometallic Single-Molecule Magnets - p. iii 9. 1.09. Electrochemistry in Organometallic Chemistry - p. iii 10. 1.10. Organometallic Photosensitizers - p. iii 11. 1.11. Organometallic Chemistry of NHCs and Analogues - p. iii 12. 1.12. Ligands Featuring Covalently Tethered Moderate to Weakly Coordinating Anions - p. iii 13. 1.13. Redox-Active Ligands in Organometallic Chemistry - p. iii 14. 1.14. Proton Responsive and Hydrogen Bonding Ligands in Organometallic Chemistry - p. iii 15. 1.15. Introduction to the Organometallic Chemistry of Carbon Dioxide - p. iii 16. 1.16. Alkane σ-Complexes - p. iii 17. 1.17. Dinitrogen Binding and Functionalization - p. iii 18. 1.18. Lewis Acid Participation in Organometallic Chemistry - p. iii 19. 1.19. Organometallic Chemistry on Oxide Surfaces - p. iii 20. 1.20. Separation Strategies in Organometallic Catalysis - p. iii 21. 1.21. Impurities in Organometallic Catalysis - p. iii 22. 2.01. Introduction to Groups 1 to 2 - p. iii 23. 2.02. Organometallic Complexes of the Alkali Metals - p. iii 24. 2.03. Organometallic Complexes of the Alkaline Earth Metals - p. iii 25. Abstract - p. iii 26. Abbreviations - p. iii 27. Acknowledgments - p. iii 28. 2.03.1 Introduction - p. iii 29. 2.03.2 Beryllium - p. iii 30. 2.03.3 Magnesium - p. iii 31. 2.03.4 Calcium - p. iii 32. 2.03.5 Strontium and barium - p. iii 33. 2.03.6 Concluding remarks - p. iii 34. References - p. iii 35. 3.01. Introduction to Groups 3 to 4 and the f-Elements - p. iii 36. 3.02. Alkyl, carbonyl and cyanide complexes of the group 3 metals and lanthanides - p. iii 37. 3.03. Hydride, Alkyl, Aryl, Acetylide, Carbonyl, and Cyanide Complexes of the Actinides - p. iii 38. 3.04. Alkyl, Carbonyl and Cyanide Complexes of the Group 4 Metals - p. iii 39. N-Heterocyclic and Abnormal/Mesoionic Carbene Complexes of the Group 3 Metals and Lanthanides - p. iii 40. 3.06. N-Heterocyclic and Mesoionic Carbene Complexes of the Actinides - p. iii 41. 3.07. N-Heterocyclic and Mesoionic Carbene Complexes of the Group 4 Metals - p. iii 42. 3.08. Alkylidene Complexes of the Group 3 Metals and Lanthanides - p. iii 43. 3.09. Actinide Metal Carbene Complexes: Synthesis, Structure and Reactivity - p. iii 44. 3.10. Alkylidene Complexes of the Group 4 Transition Metals - p. iii 45. 3.11. Alkenes and Allyl Complexes of the Group 3 Metals and Lanthanides - p. iii 46. 3.12. Alkene, Alkyne and Allyl Complexes of the Actinides - p. iii 47. 3.13. Group 4 Metal Alkyne, Alkene, and Allyl Complexes - p. iii 48. 4.01. Buta- and Pentadienyl Complexes of the Group 3 Metals and Lanthanides - p. iii 49. 4.02. Buta- and Penta-Dienyl Complexes of the Actinides - p. iii 50. 4.03. Buta- and Penta-Dienyl Complexes of the Group 4 Metals - p. iii 51. 4.04. Cyclopentadienyls and Phospholyls of the Group 3 Metals and Lanthanides - p. iii 52. Abstract - p. iii 53. Abbreviations - p. iii 54. Acknowledgments - p. iii 55. 4.04.1 Group 3 and lanthanide cyclopentadienyl complexes - p. iii 56. References - p. iii 57. 4.05. Cyclopentadienyl and phospholyl compounds in organometallic actinide chemistry - p. iii 58. 4.06. Cyclopentadienyl and Phospholyl Complexes of the Group 4 Metals - p. iii 59. Abstract - p. iii 60. Nomenclature - p. iii 61. 4.06.1 Introduction - p. iii 62. 4.06.2 Titanium - p. iii 63. 4.06.3 Zirconium - p. iii 64. 4.06.4 Hafnium - p. iii 65. 4.06.5 Closing remarks - p. iii 66. References - p. iii 67. 4.07. Arene Complexes of the Group 3 Metals and Lanthanides - p. iii 68. 4.08. Arene Complexes of the Actinides - p. iii 69. 4.09. Arene Complexes of the Group 4 Metals - p. iii 70. 4.10. Larger Aromatic Complexes of the Group 3 Metals and Lanthanides - p. iii 71. Larger Aromatic Complexes of the Actinides - p. iii 72. 4.12. Larger Aromatic Complexes of the Group 4 Metals - p. iii 73. 5.01. Overview and Introduction - p. iii 74. 5.02. Cyclic and Non-Cyclic Pi Complexes of Vanadium - p. iii 75. 5.03. Cyclic and Non-Cyclic π-Complexes of Tantalum and Niobium - p. iii 76. 5.04. Cyclic and Non-cyclic Pi Complexes of Chromium - p. iii 77. Abstract - p. iii 78. 5.04.1 Introduction - p. iii 79. 5.04.2 η6-Arene chromium complexes - p. iii 80. 5.04.3 η6-Heteroarene chromium complexes - p. iii 81. 5.04.4 Other η6-pi-ligand chromium complexes - p. iii 82. 5.04.5 η5-Cyclopentadienyl chromium complexes - p. iii 83. 5.04.6 η5-Heterocyclopentadienyl chromium complexes - p. iii 84. 5.04.7 Other η5-pi-ligand chromium complexes - p. iii 85. 5.04.8 η2-Pi-ligand chromium complexes - p. iii 86. 5.04.9 η3-Pi-ligand chromium complexes - p. iii 87. 5.04.10 η4-Pi-ligand chromium complexes - p. iii 88. 5.04.11 η7-Pi-ligand chromium complexes - p. iii 89. 5.04.12 Summaries and suggestions - p. iii 90. References - p. iii 91. 5.05. Cyclic and Non-Cyclic Pi Complexes of Molybdenum - p. iii 92. Abstract - p. iii 93. 5.05.1 Cyclic π complexes of molybdenum - p. iii 94. 5.05.2 Non-cyclic π complexes of molybdenum - p. iii 95. 5.05.3 Summary and outlook - p. iii 96. References - p. iii 97. 5.06. Cyclic and Non-Cyclic Pi Complexes of Tungsten - p. iii 98. Abstract - p. iii 99. 5.06.1 Monoalkene complexes - p. iii 100. 5.06.2 Bis-alkene complexes - p. iii 101. 5.06.3 Allyl complexes - p. iii 102. 5.06.4 Monoalkyne complexes - p. iii 103. 5.06.5 Bis-alkyne complexes - p. iii 104. 5.06.6 Tris-alkyne complexes - p. iii 105. 5.06.7 Nitriles and heteroalkyne complexes - p. iii 106. 5.06.8 Carbonyl complexes - p. iii 107. 5.06.9 Imine and iminium complexes - p. iii 108. 5.06.10 Cyclopentadienyl complexes - p. iii 109. 5.06.11 Indenyl-tungsten complexes - p. iii 110. 5.06.12 Cyclobutadiene complexes - p. iii 111. 5.06.13 Arene complexes - p. iii 112. 5.06.14 Cycloheptatrienyl complexes - p. iii 113. 5.06.15 Summary - p. iii 114. References - p. iii 115. 5.07. Cyclic and Non-Cyclic Pi Complexes of Manganese - p. iii 116. Abstract - p. iii 117. Abbreviations - p. iii 118. Acknowledgments - p. iii 119. 5.07.1 Introduction and organization - p. iii 120. 5.07.2 Acyclic π ligands - p. iii 121. 5.07.3 Cyclic π ligands - p. iii 122. 5.07.4 Concluding remarks - p. iii 123. References - p. iii 124. 5.08. Organometallic Complexes of Technetium - p. iii 125. 5.09. Organometallic Complexes of Group 5 Metals With Metal-Carbon Sigma and Multiple Bonds - p. iii 126. 5.10. Group 6 Complexes With Metal-Carbon Sigma Bonds - p. iii 127. 5.11. Group 6 High Oxidation State Alkylidene and Alkylidyne Complexes - p. iii 128. Abstract - p. iii 129. 5.11.1 Introduction - p. iii 130. 5.11.2 Alkylidene complexes - p. iii 131. 5.11.3 Alkylidyne complexes - p. iii 132. 5.11.4 Pincer alkylidenes and alkylidynes - p. iii 133. 5.11.5 NHC alkylidene and alkylidyne complexes - p. iii 134. 5.11.6 Conclusions and perspective - p. iii 135. References - p. iii 136. 6.01. Complexes of Group 7 Metals with Metal-Carbon Sigma and Multiple Bonds - p. iii 137. Abstract - p. iii 138. Nomenclature - p. iii 139. 6.01.1 Introduction - p. iii 140. 6.01.2 Alkyl complexes - p. iii 141. 6.01.3 Aryl complexes - p. iii 142. 6.01.4 Vinyl complexes - p. iii 143. 6.01.5 Alkynyl complexes - p. iii 144. 6.01.6 Acyl and related complexes - p. iii 145. 6.01.7 Carbene complexes - p. iii 146. 6.01.8 Vinylidene and allenylidene complexes - p. iii 147. 6.01.9 Carbyne complexes - p. iii 148. 6.01.10 Metallacarbocycles - p. iii 149. 6.01.11 Conclusion - p. iii 150. References - p. iii 151. N-Heterocyclic and Mesoionic Carbene Complexes of Group 5 and Group 6 Metals - p. iii 152. 6.03. N-Heterocyclic and Mesoionic Carbene Complexes of Group 7 Metals - p. iii 153. 6.04. Organometallic Complexes of Group 5 With π-Acidic Ligands - p. iii 154. 6.05. Group VI Metal Complexes of Carbon Monoxide and Isocyanides - p. iii 155. Abstract - p. iii 156. Acknowledgments - p. iii 157. 6.05.1 Introduction - p. iii 158. 6.05.2 Homoleptic carbonyl complexes - p. iii 159. 6.05.3 Alkane complexes - p. iii 160. 6.05.4 Dihydrogen, hydride, borane-Lewis base adducts and σ-alane complexes - p. iii 161. 6.05.5 Complexes with silicon-containing ligands - p. iii 162. 6.05.6 Complexes with group VI metal–boron bonds - p. iii 163. 6.05.7 Complexes with group VI metal–nitrogen bonds - p. iii 164. 6.05.8 Complexes with group VI metal–phosphorus bonds - p. iii 165. 6.05.9 Complexes with group VI metal–oxygen bonds - p. iii 166. 6.05.10 Complexes with group VI metal–halide bonds - p. iii 167. 6.05.11 Complexes with group VI metal–gallium and indium bonds - p. iii 168. 6.05.12 Complexes with group VI metal–germanium, tin and lead bonds - p. iii 169. 6.05.13 Complexes with group VI metal–arsenic, antimony and bismuth bonds - p. iii 170. 6.05.14 Complexes with group VI metal–sulfur, selenium and tellurium bonds - p. iii 171. 6.05.15 Complexes that incorporate metallocenes - p. iii 172. 6.05.16 Group VI metal isocyanide complexes - p. iii 173. 6.05.17 Concluding remarks - p. iii 174. References - p. iii 175. 6.06. Carbonyl and Isocyanide Complexes of Manganese - p. iii 176. Abstract - p. iii 177. Abbreviations - p. iii 178. 6.06.1 Introduction - p. iii 179. 6.06.2 Brief discussion about Mn-CO starting materials and their preparation - p. iii 180. 6.06.3 Mn carbonyl complexes with monodentate ligands - p. iii 181. 6.06.4 Mn carbonyl complexes supported with bidentate ligands - p. iii 182. 6.06.5 Mn carbonyl complexes with tridentate “pincer” ligands - p. iii 183. 6.06.6 Mn carbonyl complexes with facially coordinating tridentate ligands - p. iii 184. 6.06.7 Mn carbonyl complexes with tetradentate ligands - p. iii 185. 6.06.8 Multinuclear Mn complexes with μ-X ligands (e.g., phosphido, thiolato, etc.) and clusters - p. iii 186. 6.06.9 Chemistry of Mn-CNR complexes - p. iii 187. 6.06.10 Mn-CO compounds in materials and supramolecular chemistry - p. iii 188. References - p. iii 189. 6.07. Carbonyl and Isocyanide Complexes of Rhenium - p. iii 190. 6.08. Organometallic Complexes of Group 5 Metals With Pincer and Noninnocent Ligands - p. iii 191. 6.09. Organometallic Pincer Complexes With Group 6 Metals - p. iii 192. 6.10. Organometallic Complexes of Group 7 Metals With Pincer and Noninnocent Ligands - p. iii 193. 6.11. Organometallic Tri- and Polynuclear Clusters of Tantalum, Niobium and Group 6 and 7 Transition Metals - p. iii 194. Complexes of Groups 5–7 with N2, NO, and Other N-Containing Small Molecules - p. iii 195. 7.01. Introduction to Groups 8 to 10 - p. iii 196. 7.02. Ferrocenes and Other Sandwich Complexes of Iron - p. iii 197. 7.03. Monocyclopentadienyl and Other Half-Sandwich Complexes of Iron - p. iii 198. Abstract - p. iii 199. Nomenclature - p. iii 200. 7.03.1 Introduction and historical perspectives - p. iii 201. 7.03.2 Monocyclopentadienyl compounds bearing classic π-acceptor ligands L - p. iii 202. 7.03.3 Monocyclopentadienyl compounds bearing halide and pseudohalide ligands - p. iii 203. 7.03.4 Monocyclopentadienyl compounds bearing group 15 donor ligands - p. iii 204. 7.03.5 Monocyclopentadienyl compounds bearing group 16 donor ligands - p. iii 205. 7.03.6 Monocyclopentadienyl compounds bearing group 14 donor ligands - p. iii 206. 7.03.7 Monocyclopentadienyl compounds bearing group 13 donor ligands - p. iii 207. 7.03.8 Monocyclopentadienyl iron hydride compounds - p. iii 208. 7.03.9 Heterobimetallic complexes featuring iron-metal bonds - p. iii 209. 7.03.10 Conclusion - p. iii 210. References - p. iii 211. 7.04. Recent Advances in Synthesis, Characterization and Reactivities of Iron-Alkyl and Iron-Aryl Complexes - p. iii 212. 7.05. Alkylidyne and Alkylidene Complexes of Iron - p. iii 213. 7.06. Small Molecule Activation by Organo-iron Complexes - p. iii 214. 7.07. Mono- and Bis-cyclopentadienyl Complexes of Ruthenium and Osmium - p. iii 215. Abstract - p. iii 216. 7.07.1 Introduction - p. iii 217. 7.07.2 Pogo stick type (one-legged piano stool) complexes - p. iii 218. 7.07.3 Two-legged piano stool complexes - p. iii 219. 7.07.4 Three-legged piano stool complexes - p. iii 220. 7.07.5 Four-legged piano stool complexes and penta- and hexahydrido complexes of osmium - p. iii 221. 7.07.6 Metallocenes and arene complexes of ruthenium and osmium - p. iii 222. 7.07.7 Concluding remarks - p. iii 223. References - p. iii 224. Ruthenium and Osmium Complexes Containing NHC and π-Acid Ligands - p. iii 225. Abstract - p. iii 226. Nomenclature - p. iii 227. Acknowledgment - p. iii 228. 7.08.1 General introduction - p. iii 229. 7.08.2 Complexes containing NHC ligands - p. iii 230. 7.08.3 Heavier tetrylenes - p. iii 231. 7.08.4 Nitrogen coordinating ligands - p. iii 232. 7.08.5 Phosphorous coordinating ligands - p. iii 233. References - p. iii 234. Relevant Websites - p. iii 235. Ruthenium benzylidene and benzylidyne complexes: Alkene metathesis catalysis - p. iii 236. 7.10. Ruthenium and Osmium Carbonyl Cluster Complexes - p. iii 237. 7.11. N-Heterocyclic Carbene Complexes of Cobalt - p. iii 238. Abstract - p. iii 239. Abbreviations - p. iii 240. Acknowledgments - p. iii 241. 7.11.1 General introduction - p. iii 242. 7.11.2 NHC cobalt complexes - p. iii 243. 7.11.3 General conclusion - p. iii 244. References - p. iii 245. 7.12. Organocobalt Complexes in C–H Bond Activation - p. iii 246. 7.13. Organometallic Pincer Complexes of Cobalt, Rhodium, and Iridium - p. iii 247. 8.01. N-Heterocyclic Carbene (NHC) Complexes of Rhodium and Iridium - p. iii 248. 8.02. Half-Sandwich Rhodium and Iridium Complexes - p. iii 249. Abstract - p. iii 250. Acknowledgment - p. iii 251. 8.02.1 Introduction - p. iii 252. 8.02.2 Half-sandwich Rh/Ir complexes with bidentate ligand of N and/or O atoms - p. iii 253. 8.02.3 Half-sandwich Rh/Ir complexes with phosphorus ligands - p. iii 254. 8.02.4 Half-sandwich Rh/Ir complexes with sulfur ligands - p. iii 255. 8.02.5 Half-sandwich rhodium-carbon or iridium-carbon bonded complexes - p. iii 256. 8.02.6 Half-sandwich Rh/Ir complexes bearing hydrogen, borane and metal groups - p. iii 257. 8.02.7 Half-sandwich Rh/Ir fragments in supramolecular chemistry - p. iii 258. 8.02.8 Conclusion - p. iii 259. References - p. iii 260. 8.03. Group 9 Boryl Complexes - p. iii 261. 8.04. Group 9 and 10 Carbonyl Clusters - p. iii 262. 8.05. Nickel-Carbon σ-Bonded Complexes - p. iii 263. Abstract - p. iii 264. 8.05.1 Introduction - p. iii 265. 8.05.2 Organonickel(II) complexes stabilized by tridentate ligands - p. iii 266. 8.05.3 Organonickel(II) complexes stabilized by bidentate ligands - p. iii 267. 8.05.4 Organonickel(II) complexes stabilized by monodentate ligands - p. iii 268. 8.05.5 Low-valent nickel complexes - p. iii 269. 8.05.6 High-valent nickel complexes - p. iii 270. 8.05.7 Dinuclear and mixed-valent nickel complexes - p. iii 271. 8.05.8 Conclusions and outlook - p. iii 272. References - p. iii 273. 8.06. Cyclopentadienyl Nickel Complexes - p. iii 274. 8.07. N-Heterocyclic Carbene Complexes of Nickel - p. iii 275. Abstract - p. iii 276. Abbreviations - p. iii 277. Acknowledgments - p. iii 278. 8.07.1 General Introduction - p. iii 279. 8.07.2 The Ni–N-heterocyclic carbene complexes - p. iii 280. 8.07.3 General Conclusion - p. iii 281. References - p. iii 282. 8.08. Palladium and Platinum NHC Complexes - p. iii 283. 8.09. Allyl-Palladium Complexes in Organic Synthesis - p. iii 284. 8.10. Zerovalent Nickel Organometallic Complexes - p. iii 285. 8.11. Monovalent Group 10 Organometallic Complexes - p. iii 286. 8.12. Trivalent and Tetravalent Palladium and Platinum Organometallic Complexes - p. iii 287. 9.01. Organometallic Complexes of Copper - p. iii 288. 9.02. Silver Organometallics - p. iii 289. 9.03. Zinc, Cadmium and Mercury - p. iii 290. 9.04. Recent Development in the Solution-State Chemistry of Boranes and Diboranes - p. iii 291. 9.05. Polyhedral Boranes and Carboranes - p. iii 292. 9.06. Polyhedral Metallaboranes and Metallacarboranes - p. iii 293. Abstract - p. iii 294. Nomenclature - p. iii 295. Acknowledgments - p. iii 296. 9.06.1 Introduction - p. iii 297. 9.06.2 Metallaborane clusters - p. iii 298. 9.06.3 Metallacarborane clusters - p. iii 299. 9.06.4 Supra-icosahedral metallaborane and metallacarborane clusters (Table 17) - p. iii 300. References - p. iii 301. 9.07. Gallium, Indium, and Thallium - p. iii 302. 10.01. Low-Valent Silicon Compounds - p. iii 303. 10.02. Compounds With Bonds Between Silicon and d-Block Metal Atoms - p. iii 304. 10.03. Organometallic Compounds of Germanium - p. iii 305. Abstract - p. iii 306. Nomenclature - p. iii 307. Acknowledgments - p. iii 308. 10.03.1 Introduction - p. iii 309. 10.03.2 Compounds containing germanium carbon bonds - p. iii 310. 10.03.3 Compounds with germanium group 17 element bonds - p. iii 311. 10.03.4 Compounds with germanium–hydrogen bonds - p. iii 312. 10.03.5 Compounds with germanium-group 15 element bonds - p. iii 313. 10.03.6 Compounds with germanium-group 16 element bonds - p. iii 314. 10.03.7 Compounds with germanium–metal (or metalloid) bonds - p. iii 315. 10.03.8 Germanium containing polymers - p. iii 316. 10.03.9 Germylenes - p. iii 317. 10.03.10 Compounds with germanium-germanium single bonds - p. iii 318. 10.03.11 Compounds with germanium-germanium multiple bonds - p. iii 319. 10.03.12 Conclusion - p. iii 320. References - p. iii 321. 10.04. Organometallic Compounds of Tin and Lead - p. iii 322. 10.05. Organometallic Compounds of Arsenic, Antimony and Bismuth - p. iii 323. 10.06. Frustrated Lewis Pair Systems - p. iii 324. Abstract - p. iii 325. 10.06.1 Introduction - p. iii 326. 10.06.2 Bond activation - p. iii 327. 10.06.3 Main group FLPs beyond phosphine-borane pairs - p. iii 328. 10.06.4 FLPs in catalysis - p. iii 329. 10.06.5 Mechanistic considerations - p. iii 330. 10.06.6 Transition metal Frustrated Lewis Pairs - p. iii 331. 10.06.7 Recent approaches and revising FLP-like systems - p. iii 332. 10.06.8 Conclusions - p. iii 333. References - p. iii 334. 11.01. Overview and Introduction - p. iii 335. 11.02. Lithium Complexes in Organic Synthesis - p. iii 336. 11.03. Sodium and Potassium Complexes in Organic Synthesis - p. iii 337. 11.04. Magnesium Complexes in Organic Synthesis - p. iii 338. 11.05. Calcium, Strontium and Barium Complexes in Organic Synthesis - p. iii 339. 11.06. Zinc Reagents in Organic Synthesis - p. iii 340. Abstract - p. iii 341. Acknowledgments - p. iii 342. 11.06.1 Introduction - p. iii 343. 11.06.2 Preparation of organozinc compounds - p. iii 344. 11.06.3 Applications of organozinc reagents in addition reactions - p. iii 345. 11.06.4 Applications of organozinc reagents in substitution reactions - p. iii 346. 11.06.5 Application of organozinc reagents in cross-coupling reactions - p. iii 347. 11.06.6 Catalytic applications using organozinc reagents - p. iii 348. 11.06.7 Reactivity of molecular zinc hydrides - p. iii 349. 11.06.8 Reactivity and applications of N-heterocyclic carbene zinc complexes - p. iii 350. 11.06.9 Organozinc pivalates as enhanced air- and moisture-stability reagents - p. iii 351. 11.06.10 Reactivity of heterometallic organozinc compounds - p. iii 352. 11.06.11 Conclusions - p. iii 353. References - p. iii 354. 11.07. Boron Complexes in Organic Synthesis - p. iii 355. Aluminum Complexes in Organic Synthesis - p. iii 356. 11.09. Gallium and Indium Complexes in Organic Synthesis - p. iii 357. 11.10. Silicon and Germanium Complexes in Organic Synthesis - p. iii 358. 11.11. Tin and Lead in Organic Synthesis - p. iii 359. 11.12. Antimony and Bismuth Complexes in Organic Synthesis - p. iii 360. 11.13. Selenium and Tellurium Complexes in Organic Synthesis - p. iii 361. 11.14. Frustrated Lewis Pairs in Organic Synthesis - p. iii 362. 11.15. Synergistic Effects of Multimetallic Main Group Complexes in Organic Synthesis - p. iii 363. 11.16. Main Group Complexes in Polymer Synthesis - p. iii 364. 12.01. Volume 12 and 13: Applications II. d- and f- Block Metal Complexes in Organic Synthesis - p. iii 365. 12.02. CC Bond Formation Through Heck-Like Reactions - p. iii 366. 12.03. Metal-Mediated Reductive C–C Coupling of π Bonds - p. iii 367. 12.04. C–C Bond Formation Through Cross-Electrophile Coupling Reactions - p. iii 368. 12.05. CC Bond Formation Through C-H Activation - p. iii 369. 12.06. Direct C–E (E = Boron, Halogen, Oxygen) Bond Formation Through C–H Activation - p. iii 370. 12.07. Synthetic Applications of Carbene and Nitrene CH Insertion - p. iii 371. 12.08. Metal-Catalyzed Amination: CN Bond Formation - p. iii 372. 12.09. Synthetic Applications of CC Bond Activation Reactions - p. iii 373. 12.10. Synthetic Applications of C–O and C–E Bond Activation Reactions - p. iii 374. 12.11. CF Bond Activation Reactions - p. iii 375. 12.12. Polymerization Reactions via Cross Coupling - p. iii 376. 13.01. Phosphine Ligand Development for Homogeneous Asymmetric Hydrogenation - p. iii 377. 13.02. Hydrometallation of Organometallic Complexes - p. iii 378. 13.03. Metal-Catalyzed Aerobic Oxidation Reactions - p. iii 379. 13.04. Metal-Mediated and Catalyzed Difunctionalization of Unsaturated Organics - p. iii 380. 13.05. Hydroformylation: Alternatives to Rh and Syn-gas - p. iii 381. 13.06. Reactions of Ylides Generated from MC Bonds - p. iii 382. E vs Z Selectivity in Olefin Metathesis Through Catalyst Design - p. iii 383. 13.08. Single-Electron Strategies in Organometallic Methods: Photoredox, Electrocatalysis, Radical Relay, and Beyond - p. iii 384. 13.09. Transition Metal-Catalyzed Copolymerization of Olefins With Polar Functional Monomers - p. iii 385. 13.10. Polymerization of Epoxides - p. iii 386. 13.11. Reaction Parameterization as a Tool for Development in Organometallic Catalysis - p. iii 387. 13.12. High-Throughput Experimentation in Organometallic Chemistry and Catalysis - p. iii 388. 14.01. Applications III. Materials Science, Nanoscience, Polymer Science and Surface Chemistry - p. iii 389. 14.02. Ferrocene and Related Metallocene Polymers - p. iii 390. 14.03. Conjugated Poly(metalla-ynes) - p. iii 391. 14.04. Organoboron and Related Group 13 Polymers - p. iii 392. 14.05. Organosilicon and Related Group 14 Polymers - p. iii 393. 14.06. Organophosphorus and Related Group 15 Polymers - p. iii 394. 14.07. Organometallic Dendrimers - p. iii 395. 14.08. Organometallic Functionalized MOFs - Reactivity and Catalysis - p. iii 396. 14.09. Organometallic Mesogens - p. iii 397. 14.10. Organometallic Complexes for Optoelectronic Applications - p. iii 398. 14.11. Organometallic Lanthanide Complexes as Single Molecule Magnets - p. iii 399. 14.12. Organometallic Receptors for Charged and Neutral Guest Species - p. iii 400. 14.13. Surface Organometallic Chemistry and Catalysis - p. iii 401. 14.14. Common Precursors and Surface Mechanisms for Atomic Layer Deposition - p. iii 402. 15.01. Introduction to Applications IV. Bio-Organometallics, Metallo-Therapy, Metallo-Diagnostics, Medicine and Environmental Chemistry - p. iii 403. 15.02. Hydrogenases and Model Complexes in Bioorganometallic Chemistry - p. iii 404. 15.03. Nitrogenases and Model Complexes in Bioorganometallic Chemistry - p. iii 405. Bioorganometallic Chemistry of Vitamin B12-Derivatives - p. iii 406. 15.05. Bioorganometallics: Artificial Metalloenzymes With Organometallic Moieties - p. iii 407. 15.06. Opportunities for interfacing organometallic catalysts with cellular metabolism - p. iii 408. 15.07. Oligonucleotide Complexes in Bioorganometallic Chemistry - p. iii 409. 15.08. Organometallic Receptors and Conjugates With Biomolecules in Bioorganometallic Chemistry - p. iii 410. 15.09. Organometallic Chemistry of Anticancer Ruthenium and Osmium Complexes - p. iii 411. 15.10. Organometallic Chemistry of Drugs Based on Technetium and Rhenium - p. iii 412. 15.11. Organometallic Chemistry of Drugs Based on Iron - p. iii 413. 15.12. Organometallic Chemistry of Gold-Based Drugs - p. iii 414. 15.13. Manganese-Based Carbon Monoxide-Releasing Molecules: A Multitude of Organometallic Pharmaceutical Candidates Primed for Further Biological Analysis - p. iii 415. 15.14. Organometallic Synthesis in Flow - p. iii 416. Index - p. iii 417. Authors - p. iii
