Condensed Matter Structural Chemistry builds on the foundational establishment of condensed matter chemistry; a new discipline to advance chemical and physical sciences by integrating multi-level structural perspectives into reaction chemistry. This book focuses on the structural chemistry branch, emphasizing the dynamic evolution of condensed matter structures under diverse conditions. It systematically explores multi-level structures—from electronic and crystal phases to defects in solids—and their critical roles in chemical reactions, supported by advanced in situ characterization techniques and emerging AI-driven condensed-matter engineering.
Sections highlights interdisciplinary connections with material and life sciences, addressing solids, liquids, and biological condensed phases, and illustrating how structural changes influence reaction pathways and outcomes. Intended for academic researchers, industrial developers, and advanced students in Chemistry, Physics, and Material Science, this book serves as a comprehensive guide to the structural underpinnings of condensed-matter reactions.
1. Title of Book - p. i 2. Cover image - p. i 3. Title page - p. ii 4. Table of Contents - p. iii 5. Copyright - p. iv 6. Contributors - p. xi 7. About the editors - p. xvii 8. Preface - p. xix 9. Part One. Solid state systems - p. P1 10. 1. Chemical behaviors regulated by spatial dimensions and microenvironmental factors - p. 3 11. 1.1 From condensed matter physics to condensed matter chemistry - p. 3 12. 1.2 Spatial dimensions of solid-state systems - p. 5 13. 1.3 Structural chemistry in condensed matter - p. 13 14. 1.4 Dimensions of defects - p. 26 15. 1.5 Microenvironmental factors - p. 31 16. 1.6 New chemical methods inspired by condensed matter physics - p. 45 17. 1.7 Conclusion and outlook - p. 51 18. 2. Hemilability in heterogeneous catalysis: Dynamic evolution of catalyst structure under steady-state conditions - p. 65 19. 3. Condense phase reaction under confinement - p. 85 20. 4. Control of atomic condensed states in multimetallic nanoparticles and their catalytic effects - p. 103 21. 5. Interface regulation in electrocatalytic carbon dioxide reduction - p. 143 22. 6. Condensed matter chemistry in macromolecular phase separation and self-assembly - p. 199 23. 7. Amorphous state structural chemistry - p. 231 24. Part Two. Advanced research methods - p. P2 25. 8. Condensed matter chemistry perspective on electrochemical solid/liquid interface - p. 287 26. 9. Neutron scattering studies of condensed matter chemistry - p. 331 27. 10. Application and prospects of artificial intelligence in condensed matter structural chemistry - p. 367 28. Part Three. Liquid systems - p. P3 29. 11. Structural chemistry of condensed matter under subcritical or supercritical hydrothermal conditions - p. 409 30. 12. Liquid condensed matter modulated dispersoids: From structure to functions - p. 457 31. 13. Recent advances in the condensed phase structure of the “magic solvent” hexafluoroisopropanol and its effects on chemical reactions - p. 487 32. 14. Solvent-structured effects on homogeneous organic reactions - p. 503 33. 15. Multilevel structures of ionic liquids and their role in chemical reactions - p. 519 34. Part Four. Biological systems - p. P4 35. 16. Spatial and electronic structure of proteins - p. 569 36. 17. Molecular grammar of biomolecular condensate formation - p. 605 37. 17.1 Multivalent interactions among biomacromolecular phase separation - p. 605 38. 17.2 The driving forces of phase separation - p. 610 39. 17.3 Computational latent grammar - p. 619 40. 17.4 Regulation of biomolecular condensates - p. 624 41. 17.5 Structural heterogeneity of biomolecular condensates - p. 640 42. 17.6 Conclusion - p. 642 43. 18. Nucleic acid conformation and biofunction in a macromolecular crowding environment - p. 669 44. 19. Condensed structures of polysaccharides and the relevant functions - p. 701 45. 20. Multihierarchical structural characterization of biological condensed matters - p. 739 46. Index - p. 768
Condensed Matter Structural Chemistry builds on the foundational establishment of condensed matter chemistry; a new discipline to advance chemical and physical sciences by integrating multi-level structural perspectives into reaction chemistry. This book focuses on the structural chemistry branch, emphasizing the dynamic evolution of condensed matter structures under diverse conditions. It systematically explores multi-level structures—from electronic and crystal phases to defects in solids—and their critical roles in chemical reactions, supported by advanced in situ characterization techniques and emerging AI-driven condensed-matter engineering.
Sections highlights interdisciplinary connections with material and life sciences, addressing solids, liquids, and biological condensed phases, and illustrating how structural changes influence reaction pathways and outcomes. Intended for academic researchers, industrial developers, and advanced students in Chemistry, Physics, and Material Science, this book serves as a comprehensive guide to the structural underpinnings of condensed-matter reactions.
1. Title of Book - p. i 2. Cover image - p. i 3. Title page - p. ii 4. Table of Contents - p. iii 5. Copyright - p. iv 6. Contributors - p. xi 7. About the editors - p. xvii 8. Preface - p. xix 9. Part One. Solid state systems - p. P1 10. 1. Chemical behaviors regulated by spatial dimensions and microenvironmental factors - p. 3 11. 1.1 From condensed matter physics to condensed matter chemistry - p. 3 12. 1.2 Spatial dimensions of solid-state systems - p. 5 13. 1.3 Structural chemistry in condensed matter - p. 13 14. 1.4 Dimensions of defects - p. 26 15. 1.5 Microenvironmental factors - p. 31 16. 1.6 New chemical methods inspired by condensed matter physics - p. 45 17. 1.7 Conclusion and outlook - p. 51 18. 2. Hemilability in heterogeneous catalysis: Dynamic evolution of catalyst structure under steady-state conditions - p. 65 19. 3. Condense phase reaction under confinement - p. 85 20. 4. Control of atomic condensed states in multimetallic nanoparticles and their catalytic effects - p. 103 21. 5. Interface regulation in electrocatalytic carbon dioxide reduction - p. 143 22. 6. Condensed matter chemistry in macromolecular phase separation and self-assembly - p. 199 23. 7. Amorphous state structural chemistry - p. 231 24. Part Two. Advanced research methods - p. P2 25. 8. Condensed matter chemistry perspective on electrochemical solid/liquid interface - p. 287 26. 9. Neutron scattering studies of condensed matter chemistry - p. 331 27. 10. Application and prospects of artificial intelligence in condensed matter structural chemistry - p. 367 28. Part Three. Liquid systems - p. P3 29. 11. Structural chemistry of condensed matter under subcritical or supercritical hydrothermal conditions - p. 409 30. 12. Liquid condensed matter modulated dispersoids: From structure to functions - p. 457 31. 13. Recent advances in the condensed phase structure of the “magic solvent” hexafluoroisopropanol and its effects on chemical reactions - p. 487 32. 14. Solvent-structured effects on homogeneous organic reactions - p. 503 33. 15. Multilevel structures of ionic liquids and their role in chemical reactions - p. 519 34. Part Four. Biological systems - p. P4 35. 16. Spatial and electronic structure of proteins - p. 569 36. 17. Molecular grammar of biomolecular condensate formation - p. 605 37. 17.1 Multivalent interactions among biomacromolecular phase separation - p. 605 38. 17.2 The driving forces of phase separation - p. 610 39. 17.3 Computational latent grammar - p. 619 40. 17.4 Regulation of biomolecular condensates - p. 624 41. 17.5 Structural heterogeneity of biomolecular condensates - p. 640 42. 17.6 Conclusion - p. 642 43. 18. Nucleic acid conformation and biofunction in a macromolecular crowding environment - p. 669 44. 19. Condensed structures of polysaccharides and the relevant functions - p. 701 45. 20. Multihierarchical structural characterization of biological condensed matters - p. 739 46. Index - p. 768