Cyanoximes: Chemistry, Coordination and Organometallic Compounds and their Applications contains vast information about the use of cyanoximes as small molecules ligands in coordination, bioinorganic, and in organometallic chemistry. In addition, it presents the structural chemistry of these compounds and shows their most interesting spectroscopic properties, along with the practical aspects of their chemistry. Methods of syntheses, stereochemistry of cyanoximes ligands, their structures and properties, as well as the most interesting coordination compounds are described, as well as a broad spectrum of practical applications of both cyanoximes and their metal complexes.
These simple, low molecular weight organic molecules represent a series of new excellent ampolydentate ligands for coordination chemistry. Currently, 48 cyanoximes are known, and users will find more than two hundreds cyanoxime complexes synthesized and studied using a variety of different spectroscopic methods and X-ray analysis.
1. Chapter 1.1. Introduction - p. 3 2. Chapter 1.2. Oximes are intermediate compounds - p. 9 3. Chapter 1.3. Currently known and studied cyanoximes - p. 13 4. Chapter 1.4. Stereochemistry of cyanoximes - p. 61 5. Chapter 1.5. Deprotonation of cyanoximes and formation of colored anions - p. 93 6. Chapter 1.6. UV-visible spectra of anionic cyanoximes: solvatochromism and planochromism - p. 107 7. Chapter 1.7. Solid state structures of ionic salts of cyanoximes - p. 125 8. Chapter 1.8. Formation of unique acid-salts of cyanoximes - p. 139 9. Chapter 1.9. Ligands with two and three cyanoxime moieties - p. 149 10. Chapter 1.10. Cyanoxime anions are unique ampolidentate ligands for coordination and organometallic chemistry! - p. 163 11. Chapter 2.1. Rationale and motivation for the synthesis of metal-containing cyanoximates - p. 171 12. Chapter 2.2. Preparation of Werner-type coordination compounds involving oximes - p. 175 13. Chapter 2.3. Cyanoximates of main group metals - p. 185 14. Chapter 2.4. Transition metals cyanoximates - p. 231 15. Chapter 3.1. Purpose of synthesis and characterization of series of organometallic compounds - p. 377 16. Chapter 3.2. Organotin(IV) cyanoximates - p. 389 17. Chapter 3.3. Organoantimony(V) cyanoximates - p. 405 18. Chapter 3.4. Organotellurium(IV) compounds - p. 437 19. Chapter 3.5. Organometallic cyanoximates of transition metals - p. 441 20. Chapter 4.1. Biomedical field - p. 455 21. Chapter 4.2. Technological areas - p. 577 22. Appendix A - p. 705 23. Appendix B - p. 707 24. Appendix C - p. 711 25. Appendix D - p. 713 26. Appendix E - p. 715 27. Appendix F - p. 717 28. Appendix G - p. 719 29. Appendix H - p. 721 30. Appendix I - p. 723 31. Appendix J - p. 727 32. Appendix K - p. 729 33. Appendix L - p. 731 34. Appendix M - p. 733 35. Appendix N - p. 735 36. Afterword - p. 737 37. Index - p. 743
Cyanoximes: Chemistry, Coordination and Organometallic Compounds and their Applications contains vast information about the use of cyanoximes as small molecules ligands in coordination, bioinorganic, and in organometallic chemistry. In addition, it presents the structural chemistry of these compounds and shows their most interesting spectroscopic properties, along with the practical aspects of their chemistry. Methods of syntheses, stereochemistry of cyanoximes ligands, their structures and properties, as well as the most interesting coordination compounds are described, as well as a broad spectrum of practical applications of both cyanoximes and their metal complexes.
These simple, low molecular weight organic molecules represent a series of new excellent ampolydentate ligands for coordination chemistry. Currently, 48 cyanoximes are known, and users will find more than two hundreds cyanoxime complexes synthesized and studied using a variety of different spectroscopic methods and X-ray analysis.
1. Chapter 1.1. Introduction - p. 3 2. Chapter 1.2. Oximes are intermediate compounds - p. 9 3. Chapter 1.3. Currently known and studied cyanoximes - p. 13 4. Chapter 1.4. Stereochemistry of cyanoximes - p. 61 5. Chapter 1.5. Deprotonation of cyanoximes and formation of colored anions - p. 93 6. Chapter 1.6. UV-visible spectra of anionic cyanoximes: solvatochromism and planochromism - p. 107 7. Chapter 1.7. Solid state structures of ionic salts of cyanoximes - p. 125 8. Chapter 1.8. Formation of unique acid-salts of cyanoximes - p. 139 9. Chapter 1.9. Ligands with two and three cyanoxime moieties - p. 149 10. Chapter 1.10. Cyanoxime anions are unique ampolidentate ligands for coordination and organometallic chemistry! - p. 163 11. Chapter 2.1. Rationale and motivation for the synthesis of metal-containing cyanoximates - p. 171 12. Chapter 2.2. Preparation of Werner-type coordination compounds involving oximes - p. 175 13. Chapter 2.3. Cyanoximates of main group metals - p. 185 14. Chapter 2.4. Transition metals cyanoximates - p. 231 15. Chapter 3.1. Purpose of synthesis and characterization of series of organometallic compounds - p. 377 16. Chapter 3.2. Organotin(IV) cyanoximates - p. 389 17. Chapter 3.3. Organoantimony(V) cyanoximates - p. 405 18. Chapter 3.4. Organotellurium(IV) compounds - p. 437 19. Chapter 3.5. Organometallic cyanoximates of transition metals - p. 441 20. Chapter 4.1. Biomedical field - p. 455 21. Chapter 4.2. Technological areas - p. 577 22. Appendix A - p. 705 23. Appendix B - p. 707 24. Appendix C - p. 711 25. Appendix D - p. 713 26. Appendix E - p. 715 27. Appendix F - p. 717 28. Appendix G - p. 719 29. Appendix H - p. 721 30. Appendix I - p. 723 31. Appendix J - p. 727 32. Appendix K - p. 729 33. Appendix L - p. 731 34. Appendix M - p. 733 35. Appendix N - p. 735 36. Afterword - p. 737 37. Index - p. 743
