Fundamental Coordination Ability of s-Block Metal Ions: New Aspects and Its Role in Solution Reactions delves into the intricate reaction chemistry and coordination chemistry of s-block metal ions in various solutions. This book explores the crystallization and subsequent re-dissolution of s-block metal compounds from solutions, as well as their structures and the biochemistry of these ions in living organisms. By examining the complex formation of s-block metal ions with crown ethers, the book highlights the significant advancements in host-guest chemistry involving s-block metal ions. Additionally, it discusses recent synthesization of lighter metal coordination polymers, and more.
The complex formation of s-block metal ions with crown ethers was discovered by C. J. Pedersen in 1967, and since then, host-guest chemistry of s-block metal ions have been highly developed. In recent years, many lighter metal coordination polymers have been synthesized actively. In this book, some “salt effects” or abnormal phenomena are accounted for in terms of coordination interaction with s-block metal ions in solution. The mechanism of enhanced oxidation ability of dilute nitric acid is discussed and the dissolution of pure gold in seawater with nitric acid is demonstrated. This important reference book will be useful to inorganic chemists, specifically those working in solution chemistry, main group metal chemistry and supramolecular chemistry, both in industry and academia.
1. Title of Book - p. i 2. Cover image - p. i 3. Title page - p. ii 4. Table of Contents - p. iii 5. Copyright - p. iv 6. List of contributors - p. xi 7. Part I: Chemical interaction above electrostatic force between s-block metals and ligand ions - p. 1 8. Chapter 1. Host–guest chemistry of s-block metal ions and the development of supramolecular systems - p. 3 9. Chapter 2. Light metal coordination polymers - p. 35 10. Chapter 3. Voltammetric studies on chemical interactions of alkali metal ions with acetate and benzoate ions in acetonitrile - p. 51 11. Chapter 4. Salt effects on proton transfer from nitrophenols to amine or pyridine bases in acetonitrile - p. 63 12. Chapter 5. Elucidation of salt effects on the indicator acidity in acetonitrile - p. 81 13. Chapter 6. Direct chelate formation between alkaline earth metal ions and 1-(2-pyridylazo)-2-naphthol and related reactions in acetonitrile - p. 95 14. Chapter 7. Higher ion aggregates in low-permittivity media - p. 113 15. Chapter 8. Conductivity and spectroscopic studies of ion aggregates in higher-permittivity media - p. 133 16. Part II: Coordination phenomena of s-block metal ions in aprotic and protic solvents - p. 155 17. Ultraviolet–visible and 1H or 13C nuclear magnetic resonance spectroscopic studies on the specific interaction between lithium and tropolonate ions in acetonitrile or other solvents - p. 157 18. Interaction between protons or alkaline earth metal ions and the benzoate ion in acetonitrile studied by ultraviolet–visible and 1H and 13C nuclear magnetic resonance spectroscopies - p. 185 19. Chapter 11. Precipitation and redissolution of s-block metal salts based on coordination and “reverse coordination” with aromatic dicarboxylate, sulfonate, or disulfonate ions in acetonitrile - p. 203 20. Chapter 12. Specific coordination phenomena of alkaline earth metal ions with mono-, di-, and trisulfonates in alcohols and binary solvents - p. 233 21. Chapter 13. Strong complexing ability of alkali metal and alkaline earth metal ions with organic phosphinate and phosphates - p. 257 22. Chapter 14. Chemical interaction between alkaline earth metal ions and the benzoate or 2,6-naphthalenedicarboxylate ion in acetonitrile and alcohols - p. 285 23. Chapter 15. Coordination and “reverse coordination” of alkali metal, alkaline earth metal, and indium ions with 1,3,6-naphthalenetrisulfonate ion in protic and aprotic solvents - p. 303 24. Part III: Application of the coordination ability of s-block metals and related reactions in solution - p. 329 25. 1H and 13C nuclear magnetic resonance detection of the carbocations or zwitterions from fluoran leuco dyes or trityl chlorides on the addition of s-block metal ions - p. 331 26. Alternative mechanism of SN1 solvolysis based on the direct chemical interaction between s-block metal cations and leaving-group anions - p. 359 27. Chapter 18. Discovery of enhanced oxidation mechanism of dilute nitric acid (and pure gold dissolution in seawater) - p. 387 28. Chapter 19. Pure gold dissolution by the oxidation ability of dilute nitric and nitrous acids in the presence of abundant metal salts - p. 419 29. Pure gold and stainless steel dissolution or corrosion in dilute halic acids (HXO3, X=Cl, Br, I) solution containing abundant halide ions - p. 437 30. Chapter 21. Elucidation of specific ion association in nonaqueous solution environments - p. 459 31. Index - p. 487
Fundamental Coordination Ability of s-Block Metal Ions: New Aspects and Its Role in Solution Reactions delves into the intricate reaction chemistry and coordination chemistry of s-block metal ions in various solutions. This book explores the crystallization and subsequent re-dissolution of s-block metal compounds from solutions, as well as their structures and the biochemistry of these ions in living organisms. By examining the complex formation of s-block metal ions with crown ethers, the book highlights the significant advancements in host-guest chemistry involving s-block metal ions. Additionally, it discusses recent synthesization of lighter metal coordination polymers, and more.
The complex formation of s-block metal ions with crown ethers was discovered by C. J. Pedersen in 1967, and since then, host-guest chemistry of s-block metal ions have been highly developed. In recent years, many lighter metal coordination polymers have been synthesized actively. In this book, some “salt effects” or abnormal phenomena are accounted for in terms of coordination interaction with s-block metal ions in solution. The mechanism of enhanced oxidation ability of dilute nitric acid is discussed and the dissolution of pure gold in seawater with nitric acid is demonstrated. This important reference book will be useful to inorganic chemists, specifically those working in solution chemistry, main group metal chemistry and supramolecular chemistry, both in industry and academia.
1. Title of Book - p. i 2. Cover image - p. i 3. Title page - p. ii 4. Table of Contents - p. iii 5. Copyright - p. iv 6. List of contributors - p. xi 7. Part I: Chemical interaction above electrostatic force between s-block metals and ligand ions - p. 1 8. Chapter 1. Host–guest chemistry of s-block metal ions and the development of supramolecular systems - p. 3 9. Chapter 2. Light metal coordination polymers - p. 35 10. Chapter 3. Voltammetric studies on chemical interactions of alkali metal ions with acetate and benzoate ions in acetonitrile - p. 51 11. Chapter 4. Salt effects on proton transfer from nitrophenols to amine or pyridine bases in acetonitrile - p. 63 12. Chapter 5. Elucidation of salt effects on the indicator acidity in acetonitrile - p. 81 13. Chapter 6. Direct chelate formation between alkaline earth metal ions and 1-(2-pyridylazo)-2-naphthol and related reactions in acetonitrile - p. 95 14. Chapter 7. Higher ion aggregates in low-permittivity media - p. 113 15. Chapter 8. Conductivity and spectroscopic studies of ion aggregates in higher-permittivity media - p. 133 16. Part II: Coordination phenomena of s-block metal ions in aprotic and protic solvents - p. 155 17. Ultraviolet–visible and 1H or 13C nuclear magnetic resonance spectroscopic studies on the specific interaction between lithium and tropolonate ions in acetonitrile or other solvents - p. 157 18. Interaction between protons or alkaline earth metal ions and the benzoate ion in acetonitrile studied by ultraviolet–visible and 1H and 13C nuclear magnetic resonance spectroscopies - p. 185 19. Chapter 11. Precipitation and redissolution of s-block metal salts based on coordination and “reverse coordination” with aromatic dicarboxylate, sulfonate, or disulfonate ions in acetonitrile - p. 203 20. Chapter 12. Specific coordination phenomena of alkaline earth metal ions with mono-, di-, and trisulfonates in alcohols and binary solvents - p. 233 21. Chapter 13. Strong complexing ability of alkali metal and alkaline earth metal ions with organic phosphinate and phosphates - p. 257 22. Chapter 14. Chemical interaction between alkaline earth metal ions and the benzoate or 2,6-naphthalenedicarboxylate ion in acetonitrile and alcohols - p. 285 23. Chapter 15. Coordination and “reverse coordination” of alkali metal, alkaline earth metal, and indium ions with 1,3,6-naphthalenetrisulfonate ion in protic and aprotic solvents - p. 303 24. Part III: Application of the coordination ability of s-block metals and related reactions in solution - p. 329 25. 1H and 13C nuclear magnetic resonance detection of the carbocations or zwitterions from fluoran leuco dyes or trityl chlorides on the addition of s-block metal ions - p. 331 26. Alternative mechanism of SN1 solvolysis based on the direct chemical interaction between s-block metal cations and leaving-group anions - p. 359 27. Chapter 18. Discovery of enhanced oxidation mechanism of dilute nitric acid (and pure gold dissolution in seawater) - p. 387 28. Chapter 19. Pure gold dissolution by the oxidation ability of dilute nitric and nitrous acids in the presence of abundant metal salts - p. 419 29. Pure gold and stainless steel dissolution or corrosion in dilute halic acids (HXO3, X=Cl, Br, I) solution containing abundant halide ions - p. 437 30. Chapter 21. Elucidation of specific ion association in nonaqueous solution environments - p. 459 31. Index - p. 487
