Organometallic Chemistry of Five-Membered Heterocycles explores the synthesis, coordination modes, reactivity of coordinated five-membered monoheterocycles, and organometallic complexes of their numerous derivatives, including chelating ligands, oligomers, and macrocycles. Beginning with the introduction of organometallic compounds, this book dives deep into the reactivity of coordinated five-membered monoheterocycles and the derivatives of fundamental ligands. This book is an ideal reference for researchers working in organometallic, heterocyclic, materials, or organic chemistry, and catalysis. The readers will gain a comprehensive understanding of modern synthetic methods, reactivity trends of heteroaromatic ligands, and the methods of modern materials construction.
1. Introduction - p. ix 2. Chapter 1. Furans and benzannulated forms - p. 1 3. Chapter 2. Thiophenes, benzannulated forms, and analogs - p. 47 4. Abstract - p. 47 5. 2.1 Coordination modes - p. 48 6. 2.2 Reactivity of the η5-coordinated thiophenes - p. 110 7. 2.3 Reactivity of the η6-coordinated complexes - p. 121 8. 2.4 Reactivity of the η4-coordinated complexes - p. 126 9. 2.5 Reactivity of the η2-coordinated thiophenes - p. 134 10. 2.6 Derivatives - p. 136 11. 2.7 Conclusion - p. 212 12. References - p. 213 13. Chapter 3. Pyrroles and benzannulated forms - p. 239 14. Abstract - p. 239 15. 3.1 Coordination modes - p. 239 16. 3.2 Reactivity of the coordinated pyrroles - p. 291 17. 3.3 Derivatives - p. 318 18. 3.4 Conclusion - p. 529 19. References - p. 531 20. Chapter 4. Phospholes, benzannulated forms, and analogs - p. 565 21. Chapter 5. Siloles and analogs - p. 691 22. Chapter 6. Boroles and analogs - p. 711 23. General conclusion - p. 745 24. Index - p. 761
Organometallic Chemistry of Five-Membered Heterocycles explores the synthesis, coordination modes, reactivity of coordinated five-membered monoheterocycles, and organometallic complexes of their numerous derivatives, including chelating ligands, oligomers, and macrocycles. Beginning with the introduction of organometallic compounds, this book dives deep into the reactivity of coordinated five-membered monoheterocycles and the derivatives of fundamental ligands. This book is an ideal reference for researchers working in organometallic, heterocyclic, materials, or organic chemistry, and catalysis. The readers will gain a comprehensive understanding of modern synthetic methods, reactivity trends of heteroaromatic ligands, and the methods of modern materials construction.
1. Introduction - p. ix 2. Chapter 1. Furans and benzannulated forms - p. 1 3. Chapter 2. Thiophenes, benzannulated forms, and analogs - p. 47 4. Abstract - p. 47 5. 2.1 Coordination modes - p. 48 6. 2.2 Reactivity of the η5-coordinated thiophenes - p. 110 7. 2.3 Reactivity of the η6-coordinated complexes - p. 121 8. 2.4 Reactivity of the η4-coordinated complexes - p. 126 9. 2.5 Reactivity of the η2-coordinated thiophenes - p. 134 10. 2.6 Derivatives - p. 136 11. 2.7 Conclusion - p. 212 12. References - p. 213 13. Chapter 3. Pyrroles and benzannulated forms - p. 239 14. Abstract - p. 239 15. 3.1 Coordination modes - p. 239 16. 3.2 Reactivity of the coordinated pyrroles - p. 291 17. 3.3 Derivatives - p. 318 18. 3.4 Conclusion - p. 529 19. References - p. 531 20. Chapter 4. Phospholes, benzannulated forms, and analogs - p. 565 21. Chapter 5. Siloles and analogs - p. 691 22. Chapter 6. Boroles and analogs - p. 711 23. General conclusion - p. 745 24. Index - p. 761
