Process Safety Calculations, Second Edition remains to be an essential guide for students and practitioners in process safety engineering who are working on calculating and predicting risks and consequences. The book focuses on calculation procedures based on basic chemistry, thermodynamics, fluid dynamics, conservation equations, kinetics and practical models. It provides helpful calculations to demonstrate compliance with regulations and standards, such as Seveso directive(s)/COMAH, CLP regulation, ATEX directives, PED directives, REACH regulation, OSHA/NIOSH and UK ALARP, along with risk and consequence assessment, stoichiometry, thermodynamics, stress analysis and fluid-dynamics.
This fully revised, updated and expanded second edition follows the same organization as the first, including the original three main parts, Fundamentals, Consequence Assessment and Quantitative Risk Assessment. However, the latter part is significantly expanded, including an appendix consisting of five fundamental thematic areas belonging to the risk assessment framework, including in-depth calculations methodologies for some fundamental monothematic macro-areas of process safety.
1. Title of Book - p. i 2. Cover image - p. i 3. Title page - p. ii 4. Table of Contents - p. iii 5. Copyright - p. iii 6. Author Biography - p. iii 7. Preface to the First Edition - p. xxi 8. Preface to the Second Edition - p. xxiii 9. Part 1: Fundamentals - p. xxiii 10. Chapter 1. Chemistry of Process Safety - p. 3 11. Chapter 2. Thermodynamics and Thermochemistry of Process Safety - p. 57 12. Chapter 3. Reaction Engineering of Process Safety - p. 130 13. Chapter 4. Fluid Dynamics of Process Safety - p. 147 14. Chapter 5. Loads and Stress Analysis of Process Safety - p. 207 15. Chapter 6. Statistics and Reliability of Process Safety - p. 236 16. Part 2: Consequence Assessment - p. 258 17. Chapter 7. Source Models - p. 312 18. Abstract - p. 312 19. 7.1 Summary of Scenarios - p. 312 20. 7.2 Subcooled Liquids - p. 312 21. 7.3 Boiling Liquids - p. 279 22. 7.4 Rainout and Flashing—Liquid Droplets Formation - p. 289 23. 7.5 Carbon Dioxide: Liquid-to-Solid Transition - p. 293 24. 7.6 Gases and Vapours - p. 299 25. 7.7 Pool Formation and Liquid Evaporation - p. 308 26. 7.8 US EPA Offsite Consequence Analysis (OCA) Models - p. 311 27. 7.9 Simplified Formulas - p. 318 28. References - p. 320 29. Further reading - p. 322 30. Chapter 8. Dispersion Models - p. 323 31. Chapter 9. Fire - p. 364 32. Abstract - p. 364 33. 9.1 Summary of Scenarios - p. 364 34. 9.2 Ignition Sources - p. 362 35. 9.3 Pyrophoric Materials - p. 362 36. 9.4 Relevance and Effects of Ignition Sources - p. 363 37. 9.5 Analysis of Ignition Sources - p. 363 38. 9.6 Ignition Probability - p. 373 39. 9.7 Fire Scenarios - p. 380 40. 9.8 Fire Damage to People - p. 440 41. References - p. 440 42. Chapter 10. Explosions - p. 514 43. Abstract - p. 514 44. 10.1 Summary of Scenarios - p. 514 45. 10.2 The Explosion - p. 444 46. 10.3 Laminar Burning Velocity - p. 445 47. 10.4 Flame Speed and Turbulent Velocity - p. 446 48. 10.5 Explosion With Oxidisers Other Than Oxygen - p. 447 49. 10.6 Confined Explosion: Deflagration and Detonation - p. 447 50. 10.7 Detonation in Pipes - p. 456 51. 10.8 Reflected Shock Wave and Pressure Temporal–Spatial Distribution - p. 458 52. 10.9 Semiconfined Explosion - p. 459 53. 10.10 Unconfined Vapour Cloud Explosion - p. 464 54. 10.11 Vessels Burst - p. 498 55. 10.12 Boiling Liquid Expansion Vapour Explosion - p. 501 56. 10.13 Rapid Phase Transition (RPT) - p. 508 57. 10.14 Thermal Runway - p. 511 58. 10.15 Design and Operational Issues: Hot Spots - p. 522 59. 10.16 Pressure Piling - p. 524 60. 10.17 Drag Loads - p. 527 61. 10.18 Loads on Buildings - p. 529 62. 10.19 Blast-Resistant Structures in the QRA Framework - p. 531 63. 10.20 Hazardous Area Classification - p. 540 64. 10.21 Inerting - p. 544 65. References - p. 549 66. Further reading - p. 551 67. Chapter 11. Dust Explosions - p. 569 68. Part 3: Quantitative Risk Assessment - p. 619 69. Chapter 12. Quantitative Risk Assessment - p. 623 70. Chapter 13. Structural Dynamics of Buildings Subject to Blast Loads - p. 645 71. Chapter 14. Layer of Protection Analysis - p. 696 72. Chapter 15. Explosion Protection of Vessels and Enclosures - p. 744 73. Chapter 16. Mitigation of Toxic Risk - p. 781 74. Chapter 17. Integrity Management of Equipment Subject to Fires - p. 827 75. Index - p. 863
Process Safety Calculations, Second Edition remains to be an essential guide for students and practitioners in process safety engineering who are working on calculating and predicting risks and consequences. The book focuses on calculation procedures based on basic chemistry, thermodynamics, fluid dynamics, conservation equations, kinetics and practical models. It provides helpful calculations to demonstrate compliance with regulations and standards, such as Seveso directive(s)/COMAH, CLP regulation, ATEX directives, PED directives, REACH regulation, OSHA/NIOSH and UK ALARP, along with risk and consequence assessment, stoichiometry, thermodynamics, stress analysis and fluid-dynamics.
This fully revised, updated and expanded second edition follows the same organization as the first, including the original three main parts, Fundamentals, Consequence Assessment and Quantitative Risk Assessment. However, the latter part is significantly expanded, including an appendix consisting of five fundamental thematic areas belonging to the risk assessment framework, including in-depth calculations methodologies for some fundamental monothematic macro-areas of process safety.
1. Title of Book - p. i 2. Cover image - p. i 3. Title page - p. ii 4. Table of Contents - p. iii 5. Copyright - p. iii 6. Author Biography - p. iii 7. Preface to the First Edition - p. xxi 8. Preface to the Second Edition - p. xxiii 9. Part 1: Fundamentals - p. xxiii 10. Chapter 1. Chemistry of Process Safety - p. 3 11. Chapter 2. Thermodynamics and Thermochemistry of Process Safety - p. 57 12. Chapter 3. Reaction Engineering of Process Safety - p. 130 13. Chapter 4. Fluid Dynamics of Process Safety - p. 147 14. Chapter 5. Loads and Stress Analysis of Process Safety - p. 207 15. Chapter 6. Statistics and Reliability of Process Safety - p. 236 16. Part 2: Consequence Assessment - p. 258 17. Chapter 7. Source Models - p. 312 18. Abstract - p. 312 19. 7.1 Summary of Scenarios - p. 312 20. 7.2 Subcooled Liquids - p. 312 21. 7.3 Boiling Liquids - p. 279 22. 7.4 Rainout and Flashing—Liquid Droplets Formation - p. 289 23. 7.5 Carbon Dioxide: Liquid-to-Solid Transition - p. 293 24. 7.6 Gases and Vapours - p. 299 25. 7.7 Pool Formation and Liquid Evaporation - p. 308 26. 7.8 US EPA Offsite Consequence Analysis (OCA) Models - p. 311 27. 7.9 Simplified Formulas - p. 318 28. References - p. 320 29. Further reading - p. 322 30. Chapter 8. Dispersion Models - p. 323 31. Chapter 9. Fire - p. 364 32. Abstract - p. 364 33. 9.1 Summary of Scenarios - p. 364 34. 9.2 Ignition Sources - p. 362 35. 9.3 Pyrophoric Materials - p. 362 36. 9.4 Relevance and Effects of Ignition Sources - p. 363 37. 9.5 Analysis of Ignition Sources - p. 363 38. 9.6 Ignition Probability - p. 373 39. 9.7 Fire Scenarios - p. 380 40. 9.8 Fire Damage to People - p. 440 41. References - p. 440 42. Chapter 10. Explosions - p. 514 43. Abstract - p. 514 44. 10.1 Summary of Scenarios - p. 514 45. 10.2 The Explosion - p. 444 46. 10.3 Laminar Burning Velocity - p. 445 47. 10.4 Flame Speed and Turbulent Velocity - p. 446 48. 10.5 Explosion With Oxidisers Other Than Oxygen - p. 447 49. 10.6 Confined Explosion: Deflagration and Detonation - p. 447 50. 10.7 Detonation in Pipes - p. 456 51. 10.8 Reflected Shock Wave and Pressure Temporal–Spatial Distribution - p. 458 52. 10.9 Semiconfined Explosion - p. 459 53. 10.10 Unconfined Vapour Cloud Explosion - p. 464 54. 10.11 Vessels Burst - p. 498 55. 10.12 Boiling Liquid Expansion Vapour Explosion - p. 501 56. 10.13 Rapid Phase Transition (RPT) - p. 508 57. 10.14 Thermal Runway - p. 511 58. 10.15 Design and Operational Issues: Hot Spots - p. 522 59. 10.16 Pressure Piling - p. 524 60. 10.17 Drag Loads - p. 527 61. 10.18 Loads on Buildings - p. 529 62. 10.19 Blast-Resistant Structures in the QRA Framework - p. 531 63. 10.20 Hazardous Area Classification - p. 540 64. 10.21 Inerting - p. 544 65. References - p. 549 66. Further reading - p. 551 67. Chapter 11. Dust Explosions - p. 569 68. Part 3: Quantitative Risk Assessment - p. 619 69. Chapter 12. Quantitative Risk Assessment - p. 623 70. Chapter 13. Structural Dynamics of Buildings Subject to Blast Loads - p. 645 71. Chapter 14. Layer of Protection Analysis - p. 696 72. Chapter 15. Explosion Protection of Vessels and Enclosures - p. 744 73. Chapter 16. Mitigation of Toxic Risk - p. 781 74. Chapter 17. Integrity Management of Equipment Subject to Fires - p. 827 75. Index - p. 863