Organic Electrochemistry: Fundamentals, Modern Concepts, and Methods offers a comprehensive perspective on the essentials, methodologies, and practical applications of electrochemistry in organic chemistry. Addressing fundamental principles and applied aspects arising from the convergence of electrochemistry and organic chemistry, the book strives to deliver a broad theoretical foundation. It meticulously outlines methods and applications, catering to the interests of researchers, practitioners, and postgraduate students in these domains. With a focus on 'clean' preparative organic chemistry, sections explore the potential of electrosynthesis and elucidates the information offered by electrochemical methods, including their role in processes of biological relevance.
Additionally, it sheds light on the capabilities of electroanalytical techniques and underscores the importance of the electrochemistry of novel materials, such as organic-inorganic hybrids, organic polymers, and metal-organic frameworks in advancing the frontier of Organic Chemistry.
1. Introduction - p. xxiii 2. Chapter 1. Electrochemistry: general aspects - p. 1 3. Chapter 2. Electrochemical processes of organic compounds - p. 19 4. Chapter Spot for Chapter 2. Electrochemical deuteration of organic compounds - p. 47 5. Chapter 3. One- and multielectron transfers complicated by coupled molecular catalytic reactions - p. 51 6. Chapter 4. Electrochemistry of hydrocarbons - p. 87 7. Chapter 5. Electrochemistry of oxygen-containing compounds - p. 105 8. Chapter Spot for Chapter 5. Electrochemistry of dyes and pigments - p. 125 9. Chapter 6. Electrochemistry of nitrogen-containing compounds - p. 131 10. Chapter 7. Modern electrochemistry of heterocyclic compounds - p. 155 11. Chapter 8. Electrochemistry of aliphatic heteroatom-containing compounds - p. 177 12. Chapter 9. Electrochemistry applied to determine petroleum asphalts composition and aging process associated with organosulfur compounds - p. 199 13. Chapter 10. Electrochemistry of DNA, proteins, and carbohydrates - p. 213 14. Chapter Spot for Chapter 10. Electrochemical screening of bioactive natural products and extracts - p. 231 15. Chapter 11. Paired organic electrosynthesis: sustainability and electrode design - p. 239 16. Chapter 12. Development of electrosynthesis–organocatalysis strategies for innovative enantioselective electrochemical processes - p. 261 17. Chapter 13. Mediated convergent paired organic electrosynthesis - p. 295 18. Chapter 14. Tandem electrocatalysts for CO₂ electroreduction: focus on ethylene production - p. 315 19. Chapter 15. Electropolymerization - p. 339 20. Chapter Spot for Chapter 15. Electrochemical analysis of catalytic processes in organic chemistry - p. 363 21. Chapter 16. Electrochemistry of ionic liquids - p. 369 22. Chapter Spot for Chapter 16. Applications of deep eutectic solvents in organic electroanalysis - p. 393 23. Chapter 17. Supramolecular electrochemistry - p. 401 24. Chapter Spot for Chapter 17. Molecular machinery - p. 427 25. Chapter 18. Theoretical aspects of electron-transfer processes mediated by metal macrocyclic molecules - p. 433 26. Chapter 19. Electrochemistry of solid-state organic compounds - p. 465 27. Chapter Spot for Chapter 19. Solid-state electrochemistry of parchment and paper - p. 481 28. Chapter 20. Electrochemistry of living systems - p. 491 29. Chapter Spot for Chapter 20. Electrochemical diagnosis - p. 511 30. Chapter 21. Electrochemistry of covalent organic frameworks - p. 519 31. Chapter Spot for Chapter 21. Metal-organic frameworks - p. 543 32. Chapter 22. Electrochemistry of organic–inorganic hybrid materials - p. 549 33. Chapter Spot for Chapter 22. The Maya blue puzzle - p. 573 34. Chapter 23. Bipolar organic electrochemistry - p. 579 35. Chapter 24. Electroanalysis of organic compounds - p. 611 36. Chapter 25. Nanotechnology-based pharmaceutical electroanalysis: from traditional electrodes to nanotechnology-based platforms - p. 637 37. Chapter Spot for Chapter 25. Understanding the electrochemistry of fentanyl: mechanisms and detection - p. 657 38. Chapter 26. Miniaturized electrochemical devices: from lab to field - p. 665 39. Chapter 27. ROS in organic electrochemistry - p. 691 40. Chapter Spot for Chapter 27. Voltammetry of microparticles for in situ monitoring of the activation of anthocyanins with ROS - p. 715 41. Chapter 28. Modern electrochemical processes and systems to degrade organic contaminants in water - p. 721 42. Chapter Spot for Chapter 28. Realizing utopian sustainability - p. 747 43. Chapter 29. Organic compounds in electrical energy production and storage - p. 753 44. Chapter Spot for Chapter 29. Organic solar cells and organic transistors - p. 777 45. Index - p. 785
Organic Electrochemistry: Fundamentals, Modern Concepts, and Methods offers a comprehensive perspective on the essentials, methodologies, and practical applications of electrochemistry in organic chemistry. Addressing fundamental principles and applied aspects arising from the convergence of electrochemistry and organic chemistry, the book strives to deliver a broad theoretical foundation. It meticulously outlines methods and applications, catering to the interests of researchers, practitioners, and postgraduate students in these domains. With a focus on 'clean' preparative organic chemistry, sections explore the potential of electrosynthesis and elucidates the information offered by electrochemical methods, including their role in processes of biological relevance.
Additionally, it sheds light on the capabilities of electroanalytical techniques and underscores the importance of the electrochemistry of novel materials, such as organic-inorganic hybrids, organic polymers, and metal-organic frameworks in advancing the frontier of Organic Chemistry.
1. Introduction - p. xxiii 2. Chapter 1. Electrochemistry: general aspects - p. 1 3. Chapter 2. Electrochemical processes of organic compounds - p. 19 4. Chapter Spot for Chapter 2. Electrochemical deuteration of organic compounds - p. 47 5. Chapter 3. One- and multielectron transfers complicated by coupled molecular catalytic reactions - p. 51 6. Chapter 4. Electrochemistry of hydrocarbons - p. 87 7. Chapter 5. Electrochemistry of oxygen-containing compounds - p. 105 8. Chapter Spot for Chapter 5. Electrochemistry of dyes and pigments - p. 125 9. Chapter 6. Electrochemistry of nitrogen-containing compounds - p. 131 10. Chapter 7. Modern electrochemistry of heterocyclic compounds - p. 155 11. Chapter 8. Electrochemistry of aliphatic heteroatom-containing compounds - p. 177 12. Chapter 9. Electrochemistry applied to determine petroleum asphalts composition and aging process associated with organosulfur compounds - p. 199 13. Chapter 10. Electrochemistry of DNA, proteins, and carbohydrates - p. 213 14. Chapter Spot for Chapter 10. Electrochemical screening of bioactive natural products and extracts - p. 231 15. Chapter 11. Paired organic electrosynthesis: sustainability and electrode design - p. 239 16. Chapter 12. Development of electrosynthesis–organocatalysis strategies for innovative enantioselective electrochemical processes - p. 261 17. Chapter 13. Mediated convergent paired organic electrosynthesis - p. 295 18. Chapter 14. Tandem electrocatalysts for CO₂ electroreduction: focus on ethylene production - p. 315 19. Chapter 15. Electropolymerization - p. 339 20. Chapter Spot for Chapter 15. Electrochemical analysis of catalytic processes in organic chemistry - p. 363 21. Chapter 16. Electrochemistry of ionic liquids - p. 369 22. Chapter Spot for Chapter 16. Applications of deep eutectic solvents in organic electroanalysis - p. 393 23. Chapter 17. Supramolecular electrochemistry - p. 401 24. Chapter Spot for Chapter 17. Molecular machinery - p. 427 25. Chapter 18. Theoretical aspects of electron-transfer processes mediated by metal macrocyclic molecules - p. 433 26. Chapter 19. Electrochemistry of solid-state organic compounds - p. 465 27. Chapter Spot for Chapter 19. Solid-state electrochemistry of parchment and paper - p. 481 28. Chapter 20. Electrochemistry of living systems - p. 491 29. Chapter Spot for Chapter 20. Electrochemical diagnosis - p. 511 30. Chapter 21. Electrochemistry of covalent organic frameworks - p. 519 31. Chapter Spot for Chapter 21. Metal-organic frameworks - p. 543 32. Chapter 22. Electrochemistry of organic–inorganic hybrid materials - p. 549 33. Chapter Spot for Chapter 22. The Maya blue puzzle - p. 573 34. Chapter 23. Bipolar organic electrochemistry - p. 579 35. Chapter 24. Electroanalysis of organic compounds - p. 611 36. Chapter 25. Nanotechnology-based pharmaceutical electroanalysis: from traditional electrodes to nanotechnology-based platforms - p. 637 37. Chapter Spot for Chapter 25. Understanding the electrochemistry of fentanyl: mechanisms and detection - p. 657 38. Chapter 26. Miniaturized electrochemical devices: from lab to field - p. 665 39. Chapter 27. ROS in organic electrochemistry - p. 691 40. Chapter Spot for Chapter 27. Voltammetry of microparticles for in situ monitoring of the activation of anthocyanins with ROS - p. 715 41. Chapter 28. Modern electrochemical processes and systems to degrade organic contaminants in water - p. 721 42. Chapter Spot for Chapter 28. Realizing utopian sustainability - p. 747 43. Chapter 29. Organic compounds in electrical energy production and storage - p. 753 44. Chapter Spot for Chapter 29. Organic solar cells and organic transistors - p. 777 45. Index - p. 785
